1,2-Bis(diphenylphosphino)ethane

1,2-Bis(diphenylphosphino)ethane
dppe
Names
Preferred IUPAC name
(Ethane-1,2-diyl)bis(diphenylphosphane)
Other names
1,2-Bis(diphenylphosphino)ethane
Diphos
Dppe
Identifiers
3D model (JSmol)
761261
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.015.246 Edit this at Wikidata
EC Number
  • 216-769-2
9052
UNII
  • InChI=1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2 checkY
    Key: QFMZQPDHXULLKC-UHFFFAOYSA-N checkY
  • InChI=1/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2
    Key: QFMZQPDHXULLKC-UHFFFAOYAX
  • P(c1ccccc1)(c2ccccc2)CCP(c3ccccc3)c4ccccc4
  • c1ccc(cc1)P(CCP(c2ccccc2)c3ccccc3)c4ccccc4
Properties
C26H24P2
Molar mass 398.42 g/mol
Melting point 140 to 142 °C (284 to 288 °F; 413 to 415 K)
Hazards
GHS labelling:
GHS07: Exclamation markGHS09: Environmental hazard
Warning
H302, H315, H319, H332, H335, H410
P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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1,2-Bis(diphenylphosphino)ethane (dppe) is an organophosphorus compound with the formula (Ph2PCH2)2 (Ph = phenyl). It is a common symmetrical bidentate ligand in coordination chemistry. It is a white solid that is soluble in organic solvents.