Abexinostat
Names
IUPAC name
3-[(Dimethylamino)methyl]-N -{2-[4-(hydroxycarbamoyl)phenoxy]ethyl}-1-benzofuran-2-carboxamide
Other names
PCI-24781; CRA-024781
Identifiers
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard
100.241.399
KEGG
UNII
InChI=1S/C21H23N3O5/c1-24(2)13-17-16-5-3-4-6-18(16)29-19(17)21(26)22-11-12-28-15-9-7-14(8-10-15)20(25)23-27/h3-10,27H,11-13H2,1-2H3,(H,22,26)(H,23,25)
Y Key: MAUCONCHVWBMHK-UHFFFAOYSA-N
Y InChI=1/C21H23N3O5/c1-24(2)13-17-16-5-3-4-6-18(16)29-19(17)21(26)22-11-12-28-15-9-7-14(8-10-15)20(25)23-27/h3-10,27H,11-13H2,1-2H3,(H,22,26)(H,23,25)
Key: MAUCONCHVWBMHK-UHFFFAOYAM
O=C(NO)c3ccc(OCCNC(=O)c2oc1ccccc1c2CN(C)C)cc3
Properties
C 21 H 23 N 3 O 5
Molar mass
397.431 g·mol−1
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Abexinostat (INN ,[ 1] formerly PCI-24781 ) is an experimental drug candidate for cancer treatment.[ 2] It was developed by Pharmacyclics and licensed to Xynomic. As of 2013[update] , it was in Phase II clinical trials for B-cell lymphoma .[ 3] [needs update ] Pre-clinical study suggests the potential for treatment of different types of cancer as well.[ 4] [ 5] [ 6] [ 7]
Abexinostat exerts its effect as a pan-histone deacetylase inhibitor [ 8] [ 9] and inhibits RAD51 , which is involved in repairing DNA double strand breaks .[ 10]
^ "International Nonproprietary Names for Pharmaceutical Substances (INN)" (PDF) . 2011.
^ "Abexinostat" . NCI Cancer Dictionary .
^ "Abexinostat HCl (PCI-24781), PanHDAC-inhibitor" . Pharmacyclics . Archived from the original on 2013-10-27.
^ Bhalla, S; Balasubramanian, S; David, K; Sirisawad, M; Buggy, J; Mauro, L; Prachand, S; Miller, R; Gordon, LI; Evens, AM (2009). "PCI-24781 induces caspase and reactive oxygen species-dependent apoptosis through NF-kappaB mechanisms and is synergistic with bortezomib in lymphoma cells" . Clinical Cancer Research . 15 (10): 3354–65. doi :10.1158/1078-0432.CCR-08-2365 . PMC 2704489 . PMID 19417023 .
^ Lopez, G; Liu, J; Ren, W; Wei, W; Wang, S; Lahat, G; Zhu, QS; Bornmann, WG; McConkey, DJ; Pollock, RE; Lev, DC (2009). "Combining PCI-24781, a novel histone deacetylase inhibitor, with chemotherapy for the treatment of soft tissue sarcoma". Clinical Cancer Research . 15 (10): 3472–83. doi :10.1158/1078-0432.CCR-08-2714 . PMID 19417021 . S2CID 18862692 . (Erratum: doi :10.1158/1078-0432.CCR-15-0351 , PMID 25833311 . If the erratum has been checked and does not affect the cited material, please replace {{erratum |...}}
with {{erratum |...|checked=yes}}
. )
^ Rivera-Del Valle, N; Gao, S; Miller, CP; Fulbright, J; Gonzales, C; Sirisawad, M; Steggerda, S; Wheler, J; Balasubramanian, S; Chandra, J (2010). "PCI-24781, a Novel Hydroxamic Acid HDAC Inhibitor, Exerts Cytotoxicity and Histone Alterations via Caspase-8 and FADD in Leukemia Cells" . International Journal of Cell Biology . 2010 : 207420. doi :10.1155/2010/207420 . PMC 2817379 . PMID 20145726 .
^ Yang, C; Choy, E; Hornicek, FJ; Wood, KB; Schwab, JH; Liu, X; Mankin, H; Duan, Z (2011). "Histone deacetylase inhibitor (HDACI) PCI-24781 potentiates cytotoxic effects of doxorubicin in bone sarcoma cells". Cancer Chemotherapy and Pharmacology . 67 (2): 439–46. doi :10.1007/s00280-010-1344-7 . PMID 20461381 . S2CID 1344662 .
^ Buggy, JJ; Cao, ZA; Bass, KE; Verner, E; Balasubramanian, S; Liu, L; Schultz, BE; Young, PR; Dalrymple, SA (2006). "CRA-024781: A novel synthetic inhibitor of histone deacetylase enzymes with antitumor activity in vitro and in vivo" . Molecular Cancer Therapeutics . 5 (5): 1309–17. doi :10.1158/1535-7163.MCT-05-0442 . PMID 16731764 .
^ Adimoolam, S; Sirisawad, M; Chen, J; Thiemann, P; Ford, JM; Buggy, JJ (2007). "HDAC inhibitor PCI-24781 decreases RAD51 expression and inhibits homologous recombination" . Proceedings of the National Academy of Sciences of the United States of America . 104 (49): 19482–7. Bibcode :2007PNAS..10419482A . doi :10.1073/pnas.0707828104 . PMC 2148315 . PMID 18042714 .
^ "NCI Drug Dictionary" . National Cancer Institute .