Allotrope of boron
Figure 1: Likely crystal structures of experimentally obtained borophenes: (a) β 12 borophene (a.k.a. γ sheet or υ1/6 sheet), (b) χ 3 borophene (a.k.a. υ1/5 sheet)
Borophene is a crystalline atomic monolayer of boron , i.e., it is a two-dimensional allotrope of boron and also known as boron sheet .
First predicted by theory in the mid-1990s,[ 1]
different borophene structures were experimentally confirmed in 2015.[ 2] [ 3]
^ Boustani, Ihsan (January 1997). "New quasi-planar surfaces of bare boron". Surface Science . 370 (2–3): 355–363. Bibcode :1997SurSc.370..355B . doi :10.1016/S0039-6028(96)00969-7 .
^ Mannix, A. J.; Zhou, X.-F.; Kiraly, B.; Wood, J. D.; Alducin, D.; Myers, B. D.; Liu, X.; Fisher, B. L.; Santiago, U.; Guest, J. R.; et al. (December 17, 2015). "Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs" . Science . 350 (6267): 1513–1516. Bibcode :2015Sci...350.1513M . doi :10.1126/science.aad1080 . PMC 4922135 . PMID 26680195 .
^ Feng, Baojie; Zhang, Jin; Zhong, Qing; Li, Wenbin; Li, Shuai; Li, Hui; Cheng, Peng; Meng, Sheng; Chen, Lan; Wu, Kehui (March 28, 2016). "Experimental realization of two-dimensional boron sheets". Nature Chemistry . 8 (6): 563–568. arXiv :1512.05029 . Bibcode :2016NatCh...8..563F . doi :10.1038/nchem.2491 . PMID 27219700 . S2CID 19475989 .