Calcium sulfite

Calcium sulfite
Names
IUPAC name
Calcium sulfite
Other names
  • Sulfurous acid, calcium salt (1:1)
  • E226
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.529 Edit this at Wikidata
EC Number
  • 233-596-8
E number E226 (preservatives)
UNII
  • InChI=1S/Ca.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 checkY
  • InChI=1/Ca.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
    Key: GBAOBIBJACZTNA-NUQVWONBAU
  • [Ca+2].[O-]S([O-])=O
Properties
CaSO3
Molar mass 120.17 g/mol
Appearance White solid
Melting point 600 °C (1,112 °F; 873 K)
4.3 mg/100mL (18 °C)
3.1×10−7[1]
Hazards
Flash point Non-flammable
Related compounds
Other anions
Calcium sulfate
Other cations
Sodium sulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Calcium sulfite, or calcium sulphite, is a chemical compound, the calcium salt of sulfite with the formula CaSO3·x(H2O). Two crystalline forms are known, the hemihydrate and the tetrahydrate, respectively CaSO3·½(H2O) and CaSO3·4(H2O).[2] All forms are white solids. It is most notable as the product of flue-gas desulfurization.

  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–188. ISBN 978-1138561632.
  2. ^ Abraham Cohen; Mendel Zangen (1984). "Studies On Alkaline Earth Sulfites. Structure and Stability of the New Compound Ca3(SO3)2SO4.12H2O and Its Solid Solution In Calcium Sulfite Tetrahydrate". Chemistry Letters. 13 (7): 1051–1054. doi:10.1246/cl.1984.1051.