Chalcophyllite

Chalcophyllite
Chalcophyllite from the Ting Tang Mine, Carharrack, Cornwall, England. Photo by Rob Lavinsky
General
CategoryArsenate minerals
Formula
(repeating unit)
Cu
18
Al
2
(AsO
4
)
4
(SO
4
)
3
(OH)
24
·36(H
2
O)
[1][2][3] or
Cu
18
Al
2
(AsO
4
)
3
(SO
4
)
3
(OH)
27
·33(H
2
O)
[4][5][6]
IMA symbolChp[7]
Strunz classification8.DF.30
Dana classification43.5.14.1
Crystal systemTrigonal
Crystal classRhomboedral (3)
H-M symbol: (3)[2][3][4][6]
Space groupR3[8]
Identification
ColorBlue-green to emerald-green
Crystal habitCrystals platy and six-sided, also as rosettes, drusy, foliated or massive.
TwinningOn {1010} as twin plane.
CleavagePerfect on {0001}
FractureIrregular
Mohs scale hardness2
LusterVitreous to subadamantine, pearly on {0001}
StreakPale green
DiaphaneityTransparent to translucent
Specific gravity2.67 to 2.69[3][4][6] or 2.4 to 2.66[5]
Optical propertiesUniaxial (−)
Refractive indexnω = 1.618 to 1.632, nε = 1.552 to 1.575
PleochroismO blue-green, E almost colorless
SolubilitySoluble in acids and in ammonia
Other characteristicsCan be partially dehydrated. Alters to chrysocolla. Nonfluorescent, not radioactive
References[8][3][4][5][6]

Chalcophyllite is a rare secondary copper arsenate mineral occurring in the oxidized zones of some arsenic-bearing copper deposits. It was first described from material collected in Germany. At one time chalcophyllite from Wheal Tamar in Cornwall, England, was called tamarite, but this name is now discredited[2] (not to be confused with the amphibole mineral taramite, which is quite different). At Wheal Gorland a specimen exhibiting partial replacement of liriconite, Cu
2
Al(AsO
4
)(OH)
4
·(4H
2
O)
, by chalcophyllite has been found.[2] The mineral is named from the Greek, chalco "copper" and fyllon, "leaf", in allusion to its composition and platy structure. It is a classic Cornish mineral that can be confused with tabular spangolite.

  1. ^ "IMA Mineral List with Database of Mineral Properties".
  2. ^ a b c d Rocks & Minerals (2009) 84-5: 434 to 440
  3. ^ a b c d Handbook of Mineralogy
  4. ^ a b c d Mindat.org
  5. ^ a b c Webmineral data
  6. ^ a b c d Gaines et al (1997) Dana's New Mineralogy, Wiley
  7. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  8. ^ a b Mineralienatlas