| Clinoptilolite | |
|---|---|
 Clinoptilolite-Na | |
| General | |
| Category | Tectosilicates Zeolites |
| Formula (repeating unit) | (Na,K,Ca) 2–3Al 3(Al,Si) 2Si 13O 36•12H 2O |
| IMA symbol | Cpt[1] |
| Strunz classification | 9.GE.05 |
| Crystal system | Monoclinic |
| Space group | C2/m (no. 12) |
| Identification | |
| Mohs scale hardness | 3.5–4 |
| Luster | Vitreous |
| References | [2][3][4] |
Clinoptilolite is a natural zeolite composed of a microporous arrangement of silica and alumina tetrahedra. It has the complex formula (Na,K,Ca)
2–3Al
3(Al,Si)
2Si
13O
36•12H
2O. It forms as white, green to reddish tabular monoclinic tectosilicate crystals with a Mohs hardness of 3.5 to 4 and a specific gravity of 2.1 to 2.2. It commonly occurs as a devitrification product of volcanic glass shards in tuff and as vesicle fillings in basalts, andesites and rhyolites. It was described in 1969 from an occurrence in the Barstow Formation, San Bernardino County, California. Sodium levels in clinoptilolite are generally higher than potassium levels, as is the case with the San Bernardino Barstow Formation, but there are sources that are potassium-rich and have minimal sodium.[5]
It forms a series with heulandite:
- Clinoptilolite-Ca – heulandite-Ca solid solution series
- Clinoptilolite-K – heulandite-K solid solution series
- Clinoptilolite-Na – heulandite-Na solid solution series
Use of clinoptilolite in industry and academia focuses on its ion exchange properties having a strong exchange affinity for ammonium (NH4+). A typical example of this is in its use as an enzyme-based urea sensor.[6]
The name is derived from the Greek words klino (κλίνω; "oblique"), ptylon (φτερών; "feather"), and lithos (λίθος; "stone").
- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ Webmineral data
- ^ Mindat with location data
- ^ Smyth, J.R.; Spaid, A.T.; Bish, D.L. (1990). "Crystal structures of a natural and a Cs-exchanged clinoptilolite natural sample". American Mineralogist. 75: 522–528.
- ^ Sheppard and Gude (1969). "Geological Survey Professional Paper 634: Diagenesis of Tuffs in the Barstow Formation, Mud Hills, San Bernardino County, California" (PDF). USGS. Archived (PDF) from the original on 2017-02-02.
- ^ Saiapina, O. Y.; Pyeshkova, V. M.; Soldatkin, O. O.; Melnik, V. G.; Kurç, B. Akata; Walcarius, A.; Dzyadevych, S. V.; Jaffrezic-Renault, N. (2011-10-10). "Conductometric enzyme biosensors based on natural zeolite clinoptilolite for urea determination". Materials Science and Engineering: C. 31 (7): 1490–1497. doi:10.1016/j.msec.2011.06.003. ISSN 0928-4931.