Component (thermodynamics)

In thermodynamics, a component is one of a collection of chemically independent constituents[a][1] of a system. The number of components represents the minimum number of independent chemical species necessary to define the composition of all phases of the system.[2]

Calculating the number of components in a system is necessary when applying Gibbs' phase rule in determination of the number of degrees of freedom of a system.

The number of components is equal to the number of distinct chemical species (constituents), minus the number of chemical reactions between them, minus the number of any constraints (like charge neutrality or balance of molar quantities).


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  1. ^ "Chapter 7 Simple Mixtures". Central Michigan University. Retrieved 8 February 2024.
  2. ^ Atkins, Peter; Paula, Julio de (March 10, 2006). Physical Chemistry (8th ed.). W. H. Freeman. pp. 175–176. ISBN 9780716787594. OCLC 972057330.