The "asymmetric conduction" of electric current across electrical contacts between a crystal and a metal was discovered in 1874 by Karl Ferdinand Braun.[6] Crystals were first used as radio wave detectors in 1894 by Jagadish Chandra Bose in his microwave experiments.[7][8] Bose first patented a crystal detector in 1901.[9] The crystal detector was developed into a practical radio component mainly by G. W. Pickard,[4][10][11] who discovered crystal rectification in 1902 and found hundreds of crystalline substances that could be used in forming rectifying junctions.[2][12] The physical principles by which they worked were not understood at the time they were used,[13] but subsequent research into these primitive point contact semiconductor junctions in the 1930s and 1940s led to the development of modern semiconductor electronics.[1][4][14][15]
The unamplified radio receivers that used crystal detectors are called crystal radios.[16] The crystal radio was the first type of radio receiver that was used by the general public,[14] and became the most widely used type of radio until the 1920s.[17] It became obsolete with the development of vacuum tube receivers around 1920,[1][14] but continued to be used until World War II and remains a common educational project today thanks to its simple design.
^ abcdCite error: The named reference Braun was invoked but never defined (see the help page).
^ abCite error: The named reference Sievers1 was invoked but never defined (see the help page).
^Cite error: The named reference Hickman was invoked but never defined (see the help page).
^Seitz, Frederick; Einspruch, Norman (4 May 1998). The Tangled History of Silicon in Electronics. Silicon Materials Science and Technology: Proceedings of the Eighth International Symposium on Silicon Materials Science and Technology, Vol. 1. San Diego: The Electrochemical Society. pp. 73–74. ISBN9781566771931. Retrieved 27 June 2018.
^U.S. patent 755,840 Jagadis Chunder Bose, Detector for Electrical Disturbances, filed: 30 September 1901, granted 29 March 1904
^U.S. patent 836,531 Greenleaf Whittier Pickard, Means for Receiving Intelligence Communicated by Electric Waves, filed: 30 August 1906, granted: 20 November 1906
^"...crystal detectors have been used [in receivers] in greater numbers than any other [type of detector] since about 1907." Marriott, Robert H. (September 17, 1915). "United States Radio Development". Proceedings of the Institute of Radio Engineers. 5 (3): 184. doi:10.1109/jrproc.1917.217311. S2CID51644366. Retrieved 2010-01-19.