Entropy

Thermodynamics
The classical Carnot heat engine
Branches Classical Statistical Chemical Quantum thermodynamics Equilibrium / Non-equilibrium
Laws Zeroth First Second Third
Systems Closed system Open system Isolated system State Equation of state Ideal gas Real gas State of matter Phase (matter) Equilibrium Control volume Instruments Processes Isobaric Isochoric Isothermal Adiabatic Isentropic Isenthalpic Quasistatic Polytropic Free expansion Reversibility Irreversibility Endoreversibility Cycles Heat engines Heat pumps Thermal efficiency
System properties Note: Conjugate variables in italics Property diagrams Intensive and extensive properties Process functions Work Heat Functions of state Temperature / Entropy (introduction) Pressure / Volume Chemical potential / Particle number Vapor quality Reduced properties
Material properties Property databases Specific heat capacity  ${\displaystyle c=}$ ${\displaystyle T}$ ${\displaystyle \partial S}$ ${\displaystyle N}$ ${\displaystyle \partial T}$ Compressibility  ${\displaystyle \beta =-}$ ${\displaystyle 1}$ ${\displaystyle \partial V}$ ${\displaystyle V}$ ${\displaystyle \partial p}$ Thermal expansion  ${\displaystyle \alpha =}$ ${\displaystyle 1}$ ${\displaystyle \partial V}$ ${\displaystyle V}$ ${\displaystyle \partial T}$
Equations Carnot's theorem Clausius theorem Fundamental relation Ideal gas law Maxwell relations Onsager reciprocal relations Bridgman's equations Table of thermodynamic equations
Potentials Free energy Free entropy Internal energy ${\displaystyle U(S,V)}$ Enthalpy ${\displaystyle H(S,p)=U+pV}$ Helmholtz free energy ${\displaystyle A(T,V)=U-TS}$ Gibbs free energy ${\displaystyle G(T,p)=H-TS}$
History Culture History General Entropy Gas laws "Perpetual motion" machines Philosophy Entropy and time Entropy and life Brownian ratchet Maxwell's demon Heat death paradox Loschmidt's paradox Synergetics Theories Caloric theory Vis viva ("living force") Mechanical equivalent of heat Motive power Key publications An Inquiry Concerning the Source ... Friction On the Equilibrium of Heterogeneous Substances Reflections on the Motive Power of Fire Timelines Thermodynamics Heat engines Art Education Maxwell's thermodynamic surface Entropy as energy dispersal
Scientists Bernoulli Boltzmann Bridgman Carathéodory Carnot Clapeyron Clausius de Donder Duhem Gibbs von Helmholtz Joule Kelvin Lewis Massieu Maxwell von Mayer Nernst Onsager Planck Rankine Smeaton Stahl Tait Thompson van der Waals Waterston
Other Nucleation Self-assembly Self-organization Order and disorder
Category
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Modern physics
${\displaystyle {\hat {H}}|\psi _{n}(t)\rangle =i\hbar {\frac {d}{dt}}|\psi _{n}(t)\rangle }$ ${\displaystyle G_{\mu \nu }+\Lambda g_{\mu \nu }={\kappa }T_{\mu \nu }}$ Schrödinger and Einstein field equations
Founders Max Planck Albert Einstein Niels Bohr Max Born Erwin Schrödinger Werner Heisenberg Pascual Jordan Wolfgang Pauli Paul Dirac Ernest Rutherford Louis de Broglie Satyendra Nath Bose
Concepts Topology Space Time Energy Matter Work Randomness Information Entropy Light Particle Wave
Branches Applied Experimental Theoretical Mathematical Philosophy of physics Quantum mechanics Quantum field theory Quantum information Quantum computation Electromagnetism Weak interaction Electroweak interaction Strong interaction Atomic Particle Nuclear Atomic, molecular, and optical Condensed matter Statistical Complex systems Non-linear dynamics Biophysics Neurophysics Plasma physics Special relativity General relativity Astrophysics Cosmology Theories of gravitation Quantum gravity Theory of everything
Scientists Röntgen Witten Becquerel Lorentz Planck Curie Wien Skłodowska-Curie Sommerfeld Rutherford Soddy Onnes Einstein Wilczek Born Weyl Bohr Kramers Schrödinger de Broglie Laue Bose Compton Pauli Walton Fermi van der Waals Heisenberg Dyson Zeeman Moseley Hilbert Gödel Jordan Dirac Wigner Hawking P. W. Anderson Lemaître Thomson Poincaré Wheeler Penrose Millikan Nambu von Neumann Higgs Hahn Feynman Yang Lee Lenard Salam 't Hooft Veltman Bell Gell-Mann J. J. Thomson Raman Bragg Bardeen Shockley Chadwick Lawrence Zeilinger Goudsmit Uhlenbeck
Categories Modern physics
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Entropy is a scientific concept that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication.^[1]

Entropy is central to the second law of thermodynamics, which states that the entropy of an isolated system left to spontaneous evolution cannot decrease with time. As a result, isolated systems evolve toward thermodynamic equilibrium, where the entropy is highest. A consequence of the second law of thermodynamics is that certain processes are irreversible.

The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names thermodynamic function and heat-potential.^[2] In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of heat to the instantaneous temperature. He initially described it as transformation-content, in German Verwandlungsinhalt, and later coined the term entropy from a Greek word for transformation.^[3]

Austrian physicist Ludwig Boltzmann explained entropy as the measure of the number of possible microscopic arrangements or states of individual atoms and molecules of a system that comply with the macroscopic condition of the system. He thereby introduced the concept of statistical disorder and probability distributions into a new field of thermodynamics, called statistical mechanics, and found the link between the microscopic interactions, which fluctuate about an average configuration, to the macroscopically observable behavior, in form of a simple logarithmic law, with a proportionality constant, the Boltzmann constant, that has become one of the defining universal constants for the modern International System of Units (SI).