Flerovium

Flerovium, 114Fl
Flerovium
Pronunciation
Mass number[289] (unconfirmed: 290)
Flerovium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Pb
↑
Fl
↓
—
nihonium ← flerovium → moscovium
Atomic number (Z)114
Groupgroup 14 (carbon group)
Periodperiod 7
Block  p-block
Electron configuration[Rn] 5f14 6d10 7s2 7p2 (predicted)[3]
Electrons per shell2, 8, 18, 32, 32, 18, 4 (predicted)
Physical properties
Phase at STPliquid (predicted)[4]
Melting point284 ± 50 K ​(11 ± 50 °C, ​52 ± 90 °F) (predicted)[4]
Density (near r.t.)11.4 ± 0.3 g/cm3 (predicted)[4]
Heat of vaporization38 kJ/mol (predicted)[5]
Atomic properties
Oxidation statescommon: (none)
Ionization energies
  • 1st: 832.2 kJ/mol (predicted)[6]
  • 2nd: 1600 kJ/mol (predicted)[5]
  • 3rd: 3370 kJ/mol (predicted)[5]
  • (more)
Atomic radiusempirical: 180 pm (predicted)[3][5]
Covalent radius171–177 pm (extrapolated)[7]
Other properties
Natural occurrencesynthetic
CAS Number54085-16-4
History
Namingafter Joint Institute for Nuclear Research (itself named after Georgy Flyorov)[8]
DiscoveryJoint Institute for Nuclear Research (JINR) and Lawrence Livermore National Laboratory (LLNL) (1999)
Isotopes of flerovium
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
284Fl synth 2.5 ms[9][10] SF –
α 280Cn
285Fl synth 100 ms[11] α 281Cn
286Fl synth 105 ms[12] α55% 282Cn
SF45% –
287Fl synth 360 ms[12] α 283Cn
ε?[13] 287Nh
Preview warning: Infobox Fl isotopes: Decay mode not recognised, input shown unedited "dm2=ε?" cat#D
288Fl synth 653 ms α 284Cn
289Fl synth 2.1 s α 285Cn
290Fl synth 19 s?[14][15] EC 290Nh
α 286Cn
 Category: Flerovium
| references

Flerovium is a synthetic chemical element; it has symbol Fl and atomic number 114. It is an extremely radioactive, superheavy element, named after the Flerov Laboratory of Nuclear Reactions of the Joint Institute for Nuclear Research in Dubna, Russia, where the element was discovered in 1999. The lab's name, in turn, honours Russian physicist Georgy Flyorov (Флёров in Cyrillic, hence the transliteration of "yo" to "e").[16] IUPAC adopted the name on 30 May 2012. The name and symbol had previously been proposed for element 102 (nobelium), but was not accepted by IUPAC at that time.

It is a transactinide in the p-block of the periodic table. It is in period 7, the heaviest known member of the carbon group, and the last element whose chemistry has been investigated. Initial chemical studies in 2007–2008 indicated that flerovium was unexpectedly volatile for a group 14 element.[17] More recent results show that flerovium's reaction with gold is similar to that of copernicium, showing it is very volatile and may even be gaseous at standard temperature and pressure, that it would show metallic properties, consistent with being the heavier homologue of lead, and that it would be the least reactive metal in group 14. Whether flerovium behaves more like a metal or a noble gas is still unresolved as of 2024; it might also be a semiconductor.

Very little is known about flerovium, as it can only be produced one atom at a time, either through direct synthesis or through radioactive decay of even heavier elements, and all known isotopes are short-lived. Six isotopes of flerovium are known, ranging in mass number between 284 and 289; the most stable of these, 289Fl, has a half-life of ~2.1 seconds, but the unconfirmed 290Fl may have a longer half-life of 19 seconds, which would be one of the longest half-lives of any nuclide in these farthest reaches of the periodic table. Flerovium is predicted to be near the centre of the theorized island of stability, and it is expected that heavier flerovium isotopes, especially the possibly magic 298Fl, may have even longer half-lives.

  1. ^ Flerovium and Livermorium. The Periodic Table of Videos. University of Nottingham. 2 December 2011. Retrieved 4 June 2012.
  2. ^ "flerovium". Lexico UK English Dictionary UK English Dictionary UK English Dictionary. Oxford University Press. Archived from the original on 5 February 2021.
  3. ^ a b Hoffman, Darleane C.; Lee, Diana M.; Pershina, Valeria (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. ISBN 978-1-4020-3555-5.
  4. ^ a b c Florez, Edison; Smits, Odile R.; Mewes, Jan-Michael; Jerabek, Paul; Schwerdtfeger, Peter (2022). "From the gas phase to the solid state: The chemical bonding in the superheavy element flerovium". The Journal of Chemical Physics. 157. doi:10.1063/5.0097642.
  5. ^ a b c d Fricke, Burkhard (1975). "Superheavy elements: a prediction of their chemical and physical properties". Recent Impact of Physics on Inorganic Chemistry. Structure and Bonding. 21: 89–144. doi:10.1007/BFb0116498. ISBN 978-3-540-07109-9. Retrieved 4 October 2013.
  6. ^ Pershina, Valeria (30 November 2013). "Theoretical Chemistry of the Heaviest Elements". In Schädel, Matthias; Shaughnessy, Dawn (eds.). The Chemistry of Superheavy Elements (2nd ed.). Springer Science & Business Media. p. 154. ISBN 9783642374661.
  7. ^ Bonchev, Danail; Kamenska, Verginia (1981). "Predicting the Properties of the 113–120 Transactinide Elements". Journal of Physical Chemistry. 85 (9). American Chemical Society: 1177–1186. doi:10.1021/j150609a021.
  8. ^ "Element 114 is Named Flerovium and Element 116 is Named Livermorium" (Press release). IUPAC. 30 May 2012. Archived from the original on 2 June 2012.
  9. ^ Utyonkov, V.K.; et al. (2015). Synthesis of superheavy nuclei at limits of stability: 239,240Pu + 48Ca and 249–251Cf + 48Ca reactions (PDF). Super Heavy Nuclei International Symposium, Texas A & M University, College Station TX, USA, March 31 – April 02, 2015.
  10. ^ Utyonkov, V. K.; Brewer, N. T.; Oganessian, Yu. Ts.; Rykaczewski, K. P.; et al. (15 September 2015). "Experiments on the synthesis of superheavy nuclei 284Fl and 285Fl in the 239,240Pu + 48Ca reactions". Physical Review C. 92 (3): 034609. Bibcode:2015PhRvC..92c4609U. doi:10.1103/PhysRevC.92.034609.
  11. ^ Utyonkov, V. K.; Brewer, N. T.; Oganessian, Yu. Ts.; Rykaczewski, K. P.; et al. (30 January 2018). "Neutron-deficient superheavy nuclei obtained in the 240Pu+48Ca reaction". Physical Review C. 97 (14320): 1–10. Bibcode:2018PhRvC..97a4320U. doi:10.1103/PhysRevC.97.014320.
  12. ^ a b Oganessian, Yu. Ts.; Utyonkov, V. K.; Ibadullayev, D.; et al. (2022). "Investigation of 48Ca-induced reactions with 242Pu and 238U targets at the JINR Superheavy Element Factory". Physical Review C. 106 (024612). doi:10.1103/PhysRevC.106.024612.
  13. ^ Hofmann, S.; Heinz, S.; Mann, R.; Maurer, J.; et al. (2016). "Remarks on the Fission Barriers of SHN and Search for Element 120". In Peninozhkevich, Yu. E.; Sobolev, Yu. G. (eds.). Exotic Nuclei: EXON-2016 Proceedings of the International Symposium on Exotic Nuclei. Exotic Nuclei. pp. 155–164. ISBN 9789813226555.
  14. ^ Hofmann, S.; Heinz, S.; Mann, R.; Maurer, J.; et al. (2016). "Review of even element super-heavy nuclei and search for element 120". The European Physics Journal A. 2016 (52). Bibcode:2016EPJA...52..180H. doi:10.1140/epja/i2016-16180-4.
  15. ^ Kaji, Daiya; Morita, Kosuke; Morimoto, Kouji; Haba, Hiromitsu; et al. (2017). "Study of the Reaction 48Ca + 248Cm → 296Lv* at RIKEN-GARIS". Journal of the Physical Society of Japan. 86: 034201-1–7. Bibcode:2017JPSJ...86c4201K. doi:10.7566/JPSJ.86.034201.
  16. ^ "Flerovium (Fl) Properties, Applications & Research | AMERICAN ELEMENT ®". American Elements: The Materials Science Company. Retrieved 6 June 2024.
  17. ^ Cite error: The named reference 2009ex was invoked but never defined (see the help page).