Fractional crystallization (chemistry)

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Crystallization
Fundamentals
Crystal Crystal structure Nucleation
Concepts
Crystallization Crystal growth Recrystallization Seed crystal Protocrystalline Single crystal
Methods and technology
Boules Bridgman–Stockbarger method Van Arkel–de Boer process Czochralski method Epitaxy Flux method Fractional crystallization Fractional freezing Hydrothermal synthesis Kyropoulos method Laser-heated pedestal growth Micro-pulling-down Shaping processes in crystal growth Skull crucible Verneuil method Zone melting
v t e

In chemistry, fractional crystallization is a stage-wise separation technique that relies on the liquid-solid phase change. fractional crystallisation. This is an old established method which is nevertheless capable of excellent results and a description is available in "The practical Methods of organic Chemistry" by Ludwig Gattermann in 1898 and a translation was available in English by WILLIAM B. SHOBER who was a Lehigh University, USA.

This technique fractionates via differences in crystallization temperature and enables the purification of multi-component mixtures, as long as none of the constituents can act as solvents to the others. Due to the high selectivity of the solid – liquid equilibrium, very high purities can be achieved for the selected component.