Gadolinium(III) perchlorate

Gadolinium(III) perchlorate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
12731
  • InChI=1S/3ClHO4.Gd/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3
    Key: HYBHAIGYQVICOT-UHFFFAOYSA-K
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Gd+3]
Properties
Cl3GdO12
Molar mass 455.59 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Gadolinium(III) perchlorate is an inorganic compound with the chemical formula Gd(ClO4)3. It can be obtained by reacting gadolinium(III) oxide and perchloric acid (70~72%) at 80 °C.[1] It can form colorless Gd(ClO4)3·9H2O·4C4H8O2 complex crystals with 1,4-dioxane.[2] It reacts with inositol, sodium acetate, and sodium hydroxide to obtain complexes containing giant molecular clusters {Gd140}.[1] It reacts with chromium(III) chloride and 2,2'-bipyridine at pH=5.1 to obtain [GdCr(bipy)2(OH)2(H2O)6](ClO4)4·2H2O.[3]

  1. ^ a b Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng (2017-12-20). "A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family". Journal of the American Chemical Society. 139 (50): 18178–18181. doi:10.1021/jacs.7b11112. ISSN 0002-7863. Archived from the original on 2023-03-15. Retrieved 2023-03-15.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^ Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto (Apr 1961). "Notiz über die Reaktion von Dioxan mit Perchlorathydraten einiger Übergangselemente". Chemische Berichte. 94 (4): 1153–1155. doi:10.1002/cber.19610940440. ISSN 0009-2940.
  3. ^ Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun (Dec 2015). "Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand". European Journal of Inorganic Chemistry. 2015 (34): 5702–5707. doi:10.1002/ejic.201500786. ISSN 1434-1948. Retrieved 2023-03-15.{{cite journal}}: CS1 maint: multiple names: authors list (link)