Hemilability

In coordination chemistry and catalysis hemilability (hemi - half, lability - a susceptibility to change) refers to a property of many polydentate ligands which contain at least two electronically different coordinating groups, such as hard and soft donors. These hybrid or heteroditopic ligands form complexes where one coordinating group is easily displaced from the metal centre while the other group remains firmly bound; a behaviour which has been found to increase the reactivity of catalysts when compared to the use of more traditional ligands.[1][2]

  1. ^ Bader, Armin; Lindner, Ekkehard (April 1991). "Coordination chemistry and catalysis with hemilabile oxygen-phosphorus ligands". Coordination Chemistry Reviews. 108 (1): 27–110. doi:10.1016/0010-8545(91)80013-4.
  2. ^ Braunstein, Pierre; Naud, Frédéric (16 February 2001). "Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline-Based Systems". Angewandte Chemie International Edition. 40 (4): 680–699. doi:10.1002/1521-3773(20010216)40:4<680::AID-ANIE6800>3.0.CO;2-0. PMID 11241595.