Hoffman nucleation theory

Hoffman nucleation theory is a theory developed by John D. Hoffman and coworkers in the 1970s and 80s that attempts to describe the crystallization of a polymer in terms of the kinetics and thermodynamics of polymer surface nucleation.[1] The theory introduces a model where a surface of completely crystalline polymer is created and introduces surface energy parameters to describe the process. Hoffman nucleation theory is more of a starting point for polymer crystallization theory and is better known for its fundamental roles in the Hoffman–Weeks lamellar thickening and Lauritzen–Hoffman growth theory.

  1. ^ N. B. Hannay (1976). "7". Treatise on Solid State Chemistry. Vol. 3. Plenum Press. doi:10.1002/pol.1977.130150310.