Le Chatelier's principle

In chemistry, Le Chatelier's principle (pronounced UK: /lə ʃæˈtɛlj/ or US: /ˈʃɑːtəlj/), also called Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium law,[1] is a principle used to predict the effect of a change in conditions on chemical equilibrium.[2]

The principle is named after French chemist Henry Louis Le Chatelier who enunciated the principle in 1884 by extending the reasoning from the Van 't Hoff relation of how temperature variations changes the equilibrium to the variations of pressure and what's now called chemical potential,[3][4] and sometimes also credited to Karl Ferdinand Braun, who discovered it independently in 1887.[1][5] It can be defined as:

If the equilibrium of a system is disturbed by a change in one or more of the determining factors (as temperature, pressure, or concentration) the system tends to adjust itself to a new equilibrium by counteracting as far as possible the effect of the change

— Le Chatelier's principle, Merriam-Webster Dictionary

In scenarios outside thermodynamic equilibrium, there can arise phenomena in contradiction to an over-general statement of Le Chatelier's principle.

Le Chatelier's principle is sometimes alluded to in discussions of topics other than thermodynamics.

  1. ^ a b Helmenstine, Anne Marie (2020). "Le Chatelier's Principle Definition". ThoughtCo. Archived from the original on 2021-04-20. Retrieved 2022-03-09.
  2. ^ Ball, David W.; Key, Jessie A. (2014-09-16). "Shifting Equilibria: Le Chatelier's Principle". Introductory Chemistry – 1st Canadian edition. Victoria, B.C: BCcampus: OpenEd. ISBN 978-1-77420-003-2 – via opentextbc.ca.
  3. ^ Mander, Peter (2016-09-01). "Le Châtelier's principle". carnotcycle. Retrieved 2024-09-29.
  4. ^ fr:s:Page:Comptes rendus hebdomadaires des séances de l’Académie des sciences, tome 099, 1884.djvu/786
  5. ^ Kheilová, M.; Štrunc, M. (1995-01-01). "Is the Le Chatelier-Braun Principle Valid in General in Linear Nonequilibrium Thermodynamics?". 20 (1): 19–38. doi:10.1515/jnet.1995.20.1.19. ISSN 1437-4358. {{cite journal}}: Cite journal requires |journal= (help)