In Riemannian or pseudo-Riemannian geometry (in particular the Lorentzian geometry of general relativity), the Levi-Civita connection is the unique affine connection on the tangent bundle of a manifold (i.e. affine connection) that preserves the (pseudo-)Riemannian metric and is torsion-free.
The fundamental theorem of Riemannian geometry states that there is a unique connection that satisfies these properties.
In the theory of Riemannian and pseudo-Riemannian manifolds the term covariant derivative is often used for the Levi-Civita connection. The components (structure coefficients) of this connection with respect to a system of local coordinates are called Christoffel symbols.