Manganese(IV) fluoride

Manganese(IV) fluoride
Names
	IUPAC name manganese tetrafluoride
	Other names manganese(IV) fluoride
Identifiers
CAS Number	15195-58-1;
3D model (JSmol)	Interactive image;
ChemSpider	14941034;
PubChem CID	10129971;
CompTox Dashboard (EPA)	DTXSID101045561 ;
	InChI InChI=1S/4FH.Mn/ h41H;/q;;;;+4/p-4 Key: KWKYNMDHPVYLQQ-UHFFFAOYSA-J; InChI=1/4FH.Mn/h41H;/q;;;;+4/p-4 Key: KWKYNMDHPVYLQQ-XBHQNQODAK;
	SMILES [F-].[F-].[F-].[F-].[Mn+4];
Properties
Chemical formula	MnF4
Molar mass	130.93 g mol−1
Appearance	blue solid
Density	3.61 g cm−3 (calc.)
Melting point	70 °C (158 °F; 343 K) decomposes
Solubility in water	reacts violently
Structure
Crystal structure	tetragonal, tI80
Space group	I41/a (No. 88)
Lattice constant	a = 1263 pm, c = 604.9 pm
Related compounds
Other cations	Manganese(II) fluoride; Manganese(III) fluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Manganese tetrafluoride, MnF₄, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine.^[3]^[5]

^ ^a ^b ^c Müller, B. G.; Serafin, M. (1987), "Die Kristallstruktur von Mangantetrafluorid", Z. Naturforsch. B, 42 (9): 1102–6, doi:10.1515/znb-1987-0908, S2CID 95703093.
^ Hoppe, Rudolf; Dähne, Wolfgang; Klemm, Wilhelm (1961), "Mangantetrafluorid, MnF₄", Naturwissenschaften, 48 (11): 429, Bibcode:1961NW.....48..429H, doi:10.1007/BF00621676, S2CID 30724467.
^ ^a ^b WO patent 2006033480, Torisu, Junichi; Oka, Masakazu & Kuznetsov, Andrey Sergeyevich et al., "Method of manufacturing manganese tetrafluoride", published 2006-03-30, assigned to Astor Electronics and Showa Denko .
^ Edwards, A. J. (1983), "Solid-State Structures of the Binary Fluorides of the Transition Metals", Adv. Inorg. Chem. Radiochem., Advances in Inorganic Chemistry, 27: 83–112, doi:10.1016/S0898-8838(08)60105-1, ISBN 9780120236275.
^ WO patent 2009074562, Seseke-Koyro, Ulrich; Garcia-Juan, Placido & Palsherm, Stefan et al., "Process for the purification of elemental fluorine", published 2009-06-18, assigned to Solvay Fluor .

Cite error: There are <ref group=Note> tags on this page, but the references will not show without a {{reflist|group=Note}} template (see the help page).

[str-1] Müller, B. G.; Serafin, M. (1987), "Die Kristallstruktur von Mangantetrafluorid", Z. Naturforsch. B, 42 (9): 1102–6, doi:10.1515/znb-1987-0908, S2CID 95703093.

[Hoppe-2] Hoppe, Rudolf; Dähne, Wolfgang; Klemm, Wilhelm (1961), "Mangantetrafluorid, MnF₄", Naturwissenschaften, 48 (11): 429, Bibcode:1961NW.....48..429H, doi:10.1007/BF00621676, S2CID 30724467.

[AstorPrepn-3] WO patent 2006033480, Torisu, Junichi; Oka, Masakazu & Kuznetsov, Andrey Sergeyevich et al., "Method of manufacturing manganese tetrafluoride", published 2006-03-30, assigned to Astor Electronics and Showa Denko .

[4] Edwards, A. J. (1983), "Solid-State Structures of the Binary Fluorides of the Transition Metals", Adv. Inorg. Chem. Radiochem., Advances in Inorganic Chemistry, 27: 83–112, doi:10.1016/S0898-8838(08)60105-1, ISBN 9780120236275.

[SolvayPurif-6] WO patent 2009074562, Seseke-Koyro, Ulrich; Garcia-Juan, Placido & Palsherm, Stefan et al., "Process for the purification of elemental fluorine", published 2009-06-18, assigned to Solvay Fluor .

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