In organic chemistry, a methylene bridge, methylene spacer, or methanediyl group is any part of a molecule with formula −CH2−; namely, a carbon atom bound to two hydrogen atoms and connected by single bonds to two other distinct atoms in the rest of the molecule. It is the repeating unit in the skeleton of the unbranched alkanes.
A methylene bridge can also act as a bidentate ligand joining two metals in a coordination compound, such as titanium and aluminum in Tebbe's reagent.[1]
A methylene bridge is often called a methylene group or simply methylene, as in "methylene chloride" (dichloromethane CH
2Cl
2). As a bridge in other compounds, for example in cyclic compounds, it is given the name methano. However, the term methylidene group (not to be confused with the term methylene group, nor the carbene methylidene) properly applies to the CH
2 group when it is connected to the rest of the molecule by a double bond (=CH2), giving it chemical properties very distinct from those of a bridging CH
2 group.
- ^ W. A. Herrmann (1982), "The methylene bridge". In Advances in Organometallic Chemistry, volume 20, pages 195-197.