N-Butylsodium

n-Butylsodium
Names
Preferred IUPAC name
Butylsodium
Other names
1-Sodiobutane
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C4H9.Na/c1-3-4-2;/h1,3-4H2,2H3;
    Key: IRDQNLLVRXMERV-UHFFFAOYSA-N
  • CCC[CH2].[Na]
Properties
C4H9Na
Molar mass 80.106 g·mol−1
Appearance white solid[1]
Hazards
GHS labelling:
GHS02: Flammable GHS07: Exclamation mark
Danger
Related compounds
Related compounds
n-Butylpotassium n-Butyllithium
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

n-Butylsodium CH3CH2CH2CH2Na is an organometallic compound with the idealized formula NaC4H9. Like other simple organosodium compounds, it is polymeric and highly basic.[2] In contrast to n-butyllithium, n-butylsodium is only of specialized academic interest.

  1. ^ Martinez-Martinez, A. J.; Kennedy, A. R.; Mulvey, R. E.; O'Hara, C. T. (13 November 2014). "Supplementary Material for Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation". Science. 346 (6211): 834–837. Bibcode:2014Sci...346..834M. doi:10.1126/science.1259662. PMID 25395533. S2CID 206561570.
  2. ^ Schade, Christian; Bauer, Walter; Von Ragué Schleyer, Paul (November 1985). "n-Butylsodium: The preparation, properties and NMR spectra of a hydrocarbon- and tetrahydrofuran-soluble reagent". Journal of Organometallic Chemistry. 295 (3): c25–c28. doi:10.1016/0022-328X(85)80326-0.