In geometry, an octadecahedron (or octakaidecahedron) is a polyhedron with 18 faces. No octadecahedron is regular; hence, the name does not commonly refer to one specific polyhedron.
In chemistry, "the octadecahedron" commonly refers to a specific structure with C2v symmetry, the edge-contracted icosahedron, formed from a regular icosahedron with one edge contracted. It is the shape of the closo-boranate ion [B11H11]2−.