Otera's catalyst

Otera's catalyst
Skeletal formula of Otera's catalyst
Ball-and-stick model of the Otera's catalyst molecule
Names
Other names
Octabutyltetrathiocyanatostannoxane
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/8C4H9.4CNS.2O.4Sn/c8*1-3-4-2;4*2-1-3;;;;;;/h8*1,3-4H2,2H3;;;;;;;;;;/q;;;;;;;;4*-1;;;4*+1 ☒N
    Key: BCLBTLOINGPAIT-UHFFFAOYSA-N ☒N
  • CCCC[Sn]1(N(=C=S)[Sn]2(O1[Sn]3(O2[Sn](N3=C=S)(CCCC)(CCCC)N=C=S)(CCCC)CCCC)(CCCC)CCCC)(CCCC)N=C=S
Properties
C36H72N4O2S4Sn4
Molar mass 1196.08 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Otera's catalyst, named after Japanese chemist Junzo Otera, is an organostannane compound which has been used as a transesterification catalyst. This isothioscyanate compound is a member of a family of organostannanes reported by Wada and coworkers,[1] and elaborated upon by Otera and coworkers.[2]

  1. ^ Wada, M.; Nishino, M.; Okawara, R. (1965). "Preparation and properties of dialkyltin isothiocyanate derivatives". J. Organomet. Chem. 3: 70–75. doi:10.1016/S0022-328X(00)82737-0.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^ Otera, J; et al. (1991). "Novel template effects of distannoxane catalysts in highly efficient transesterification and esterification". J. Org. Chem. 56 (18): 5307–5311. doi:10.1021/jo00018a019.