Oxalate phosphate

Na2Fe(C2O4)(HPO4) crystal structure

The oxalate phosphates are chemical compounds containing oxalate and phosphate anions. They are also called oxalatophosphates or phosphate oxalates. Some oxalate-phosphate minerals found in bat guano deposits are known.[1] Oxalate phosphates can form metal organic framework compounds.

Related compounds include the arsenate oxalates,[2][3] and phosphite oxalates,[4] oxalatomethylphosphonate,[5] and potentially other oxalate phosphonates.

  1. ^ Kampf, Anthony R.; Cooper, Mark A.; Rossman, George R.; Nash, Barbara P.; Hawthorne, Frank. C.; Marty, Joe (December 2019). "Davidbrownite-(NH 4 ), (NH 4 ,K) 5 (V 4+ O) 2 (C 2 O 4 )[PO 2.75 (OH) 1.25 ] 4 ·3H 2 O, a new phosphate–oxalate mineral from the Rowley mine, Arizona, USA". Mineralogical Magazine. 83 (6): 869–877. Bibcode:2019MinM...83..869K. doi:10.1180/mgm.2019.56. ISSN 0026-461X. S2CID 202917386.
  2. ^ "Crystal Structure of Novel Layered Iron Arsenate-Oxalate (NH4)3K3[Fe2(HAsO4)2(C2O4)4]x2H2O" (PDF). Журнал структурной химии (4). 2016. doi:10.15372/JSC20160428.
  3. ^ Chakrabarti, Sandip; Green, Mark A.; Natarajan, Srinivasan (March 2002). "Hydrothermal synthesis of the first iron arsenate-oxalate [C4N2H12]2[Fe4(HAsO4)6( C2O4)2], possessing open architecture". Solid State Sciences. 4 (3): 405–412. Bibcode:2002SSSci...4..405C. doi:10.1016/S1293-2558(02)01268-2.
  4. ^ Ramaswamy, Padmini; Hegde, Nayana N.; Prabhu, Ramanath; Vidya, V. M.; Datta, Ayan; Natarajan, Srinivasan (2009-12-21). "Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium". Inorganic Chemistry. 48 (24): 11697–11711. doi:10.1021/ic901744m. ISSN 0020-1669. PMID 19911816.
  5. ^ Huang, Ya-Ling; Huang, Meow-Yu; Chan, Tsung-Han; Chang, Bor-Chen; Lii, Kwang-Hwa (June 2007). "Synthesis, Structural Characterization, and Luminescence Properties of Lanthanide Oxalatophosphonates: Na[M 3 (H 2 O) 4 (C 2 O 4 ) 4 (CH 3 PO 3 )]·2H 2 O (M = Nd and Pr)". Chemistry of Materials. 19 (13): 3232–3237. doi:10.1021/cm070602i.