Perovskite nanocrystal

Perovskite nanocrystals can emit brightly when excited by ultraviolet or blue light.  Their colors are tunable across the entire visible spectrum by changing the halide from chloride (UV/blue) to bromide (green) and iodide (red)[1]

Perovskite nanocrystals are a class of semiconductor nanocrystals, which exhibit unique characteristics that separate them from traditional quantum dots.[2][3][4][5] Perovskite nanocrystals have an ABX3 composition where A = cesium, methylammonium (MA), or formamidinium (FA); B = lead or tin; and X = chloride, bromide, or iodide.[6]

Their unique qualities largely involve their unusual band-structure which renders these materials effectively defect tolerant or able to emit brightly without surface passivation. This is in contrast to other quantum dots such as CdSe which must be passivated with an epitaxially matched shell to be bright emitters. In addition to this, lead-halide perovskite nanocrystals remain bright emitters when the size of the nanocrystal imposes only weak quantum confinement.[7][8] This enables the production of nanocrystals that exhibit narrow emission linewidths regardless of their polydispersity.

The combination of these attributes and their easy-to-perform synthesis[9][10] has resulted in numerous articles demonstrating the use of perovskite nanocrystals as both classical and quantum light sources with considerable commercial interest. Perovskite nanocrystals have been applied to numerous other optoelectronic applications[11][12] such as light emitting diodes,[13][14][15][16][17][18] lasers,[19][20] visible communication,[21] scintillators,[22][23][24] solar cells,[25][26][27] and photodetectors.[28]

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  2. ^ Kovalenko, M.V.; Protesescu, L.; Bodnarchuk, M.I. (2017-11-10). "Properties and potential optoelectronic applications of lead halide perovskite nanocrystals". Science. 358 (6364): 745–750. Bibcode:2017Sci...358..745K. doi:10.1126/science.aam7093. ISSN 0036-8075. PMID 29123061.
  3. ^ Akkerman, Q.A.; Rainò, G.; Kovalenko, M.V.; Manna, L. (May 2018). "Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals". Nature Materials. 17 (5): 394–405. Bibcode:2018NatMa..17..394A. doi:10.1038/s41563-018-0018-4. ISSN 1476-1122. PMID 29459748. S2CID 3403391.
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  5. ^ Dey, A.; Ye, J.; De, A.; Debroye, E.; Ha, S.K.; Bladt, E.; et al. (2021-07-27). "State of the Art and Prospects for Halide Perovskite Nanocrystals". ACS Nano. 15 (7): 10775–10981. doi:10.1021/acsnano.0c08903. ISSN 1936-0851. PMC 8482768. PMID 34137264.
  6. ^ Saparov, Bayrammurad; Mitzi, David B. (13 April 2016). "Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design". Chemical Reviews. 116 (7): 4558–4596. doi:10.1021/acs.chemrev.5b00715. OSTI 1593872. PMID 27040120.
  7. ^ Cite error: The named reference :2 was invoked but never defined (see the help page).
  8. ^ Cite error: The named reference :3 was invoked but never defined (see the help page).
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  10. ^ Maksym Kovalenko (award ceremony video). Rössler Prize. 2019. Retrieved 2020-01-07.
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  12. ^ "Perovskites for optoelectronics". Nature. 26 September 2019.
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  15. ^ Kim, Young-Hoon; Wolf, Christoph; Kim, Young-Tae; Cho, Himchan; Kwon, Woosung; Do, Sungan; et al. (22 June 2017). "Highly efficient light-emitting diodes of colloidal metal–halide perovskite nanocrystals beyond quantum size". ACS Nano. 11 (7): 6586–6593. doi:10.1021/acsnano.6b07617. PMID 28587467.
  16. ^ Zhao, Lianfeng; Yeh, Yao-Wen; Tran, Nhu L.; Wu, Fan; Xiao, Zhengguo; Kerner, Ross A.; et al. (23 March 2017). "Preparation of metal halide perovskite nanocrystal thin films for improved light-emitting devices". ACS Nano. 11 (4): 3957–3964. doi:10.1021/acsnano.7b00404. PMID 28332818.
  17. ^ Liu, Peizhao; Chen, Wei; Wang, Weigao; Xu, Bing; Wu, Dan; Hao, Junjie; et al. (13 June 2017). "Halide-rich synthesized cesium lead bromide perovskite nanocrystals for light-emitting diodes with improved performance". Chemistry of Materials. 29 (12): 5168–5173. doi:10.1021/acs.chemmater.7b00692.
  18. ^ Song, Jizhong; Li, Jianhai; Li, Xiaoming; Xu, Leimeng; Dong, Yuhui; Zeng, Haibo (November 2015). "Quantum dot light-emitting diodes based on inorganic perovskite cesium lead halides (CsPbX)". Advanced Materials. 27 (44): 7162–7167. Bibcode:2015AdM....27.7162S. doi:10.1002/adma.201502567. PMID 26444873. S2CID 35511467.
  19. ^ Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska; Bodnarchuk, Maryna I.; Nedelcu, Georgian; Humer, Markus; et al. (20 August 2015). "Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites". Nature Communications. 6: 8056. Bibcode:2015NatCo...6.8056Y. doi:10.1038/ncomms9056. PMC 4560790. PMID 26290056.
  20. ^ Peidong Yang; Fu, Anthony (June 2015). "Organic–inorganic perovskites: Lower threshold for nanowire lasers". Nature Materials. 14 (6): 557–558. Bibcode:2015NatMa..14..557F. doi:10.1038/nmat4291. ISSN 1476-4660. PMID 25990907.
  21. ^ "Researchers break bandwidth record for data communication using laser-based visible light". phys.org. Retrieved 2019-11-26.
  22. ^ Chen, Qiushui; Wu, Jing; Ou, Xiangyu; Huang, Bolong; Almutlaq, Jawaher; Zhumekenov, Ayan A.; et al. (September 2018). "All-inorganic perovskite nanocrystal scintillators". Nature. 561 (7721): 88–93. Bibcode:2018Natur.561...88C. doi:10.1038/s41586-018-0451-1. ISSN 0028-0836. PMID 30150772. S2CID 52096794.
  23. ^ Graham, Eleanor; Gooding, Diana; Gruszko, Julieta; Grant, Christopher; Naranjo, Brian; Winslow, Lindley (2019-07-23). "Light yield of Perovskite nanocrystal-doped liquid scintillator". Journal of Instrumentation. 14 (11): 11024. arXiv:1908.03564. Bibcode:2019JInst..14P1024G. doi:10.1088/1748-0221/14/11/P11024. S2CID 51814879.
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