Polyurethane

Polyurethane synthesis, wherein the urethane groups −NH−(C=O)−O− link the molecular units
A kitchen sponge made of polyurethane foam

Polyurethane (/ˌpɒliˈjʊərəˌθn, -jʊəˈrɛθn/;[1] often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane term does not refer to the single type of polymer but a group of polymers. Unlike polyethylene and polystyrene polyurethanes can be produced from a wide range of starting materials resulting various polymers within the same group. This chemical variety produces polyurethanes with different chemical structures leading to many different applications. These include rigid and flexible foams, and coatings, adhesives, electrical potting compounds, and fibers such as spandex and polyurethane laminate (PUL). Foams are the largest application accounting for 67% of all polyurethane produced in 2016.[2]

A polyurethane is typically produced by reacting a polymeric isocyanate with a polyol.[3] Since a polyurethane contains two types of monomers, which polymerize one after the other, they are classed as alternating copolymers. Both the isocyanates and polyols used to make a polyurethane contain two or more functional groups per molecule.

Global production in 2019 was 25 million metric tonnes,[4] accounting for about 6% of all polymers produced in that year.

  1. ^ "polyurethane". Dictionary.com Unabridged (Online). n.d.
  2. ^ Gama, Nuno; Ferreira, Artur; Barros-Timmons, Ana (27 September 2018). "Polyurethane Foams: Past, Present, and Future". Materials. 11 (10): 1841. Bibcode:2018Mate...11.1841G. doi:10.3390/ma11101841. PMC 6213201. PMID 30262722.
  3. ^ "Polyurethane". American Chemistry Council. Retrieved 2022-09-19.
  4. ^ "Polyurethane global market volume 2015-2026". Statista. Retrieved 23 July 2021.