Stopped-flow

Stopped-flow is an experimental technique for studying chemical reactions with a half time of the order of 1 ms, introduced by Britton Chance[1][2] and extended by Quentin Gibson[3] (Other techniques, such as the temperature-jump method,[4] are available for much faster processes.)

  1. ^ Chance, Britton (1951). "Rapid and Sensitive Spectrophotometry. I. The Accelerated and Stopped‐Flow Methods for the Measurement of the Reaction Kinetics and Spectra of Unstable Compounds in the Visible Region of the Spectrum". Review of Scientific Instruments. 22 (8): 619–627. doi:10.1063/1.1746019.
  2. ^ Chance, Britton; Legallais, Victor (1951). "Rapid and Sensitive Spectrophotometry. II. A Stopped‐Flow Attachment for a Stabilized Quartz Spectrophotometer". Review of Scientific Instruments. 22 (8): 627–634. doi:10.1063/1.1746020.
  3. ^ Gibson, Q. H. (1954). "Stopped-flow apparatus for the study of rapid reactions". Discussions of the Faraday Society. 17: 137. doi:10.1039/df9541700137.
  4. ^ Eigen, M. (1954). "Methods for investigation of ionic reactions in aqueous solutions with half-times as short as 10–9sec. Application to neutralization and hydrolysis reactions". Discuss. Faraday Soc. 17: 194–205. doi:10.1039/df9541700194.