Tin(IV) sulfide

Tin(IV) sulfide
Names
	IUPAC name Tin(IV) sulfide
	Other names Tin disulfide, Stannic sulfide, Mosaic gold
Identifiers
CAS Number	1315-01-1 ;
3D model (JSmol)	Interactive image; (S=Sn=S): Interactive image;
ChEBI	CHEBI:50886 ;
ECHA InfoCard	100.013.867
EC Number	215-252-9;
PubChem CID	73977; 15238661 (S=Sn=S);
UNII	YVY89V9BUH ;
CompTox Dashboard (EPA)	DTXSID101014322 ;
	InChI InChI=1S/2S.Sn/q2*-2;+4 [inchi] Key: TUTLDIXHQPSHHQ-UHFFFAOYSA-N [inchi];
	SMILES [S-2].[S-2].[Sn+4]; (S=Sn=S): S=[Sn]=S;
Properties
Chemical formula	S2Sn
Molar mass	182.83 g·mol−1
Appearance	Gold-yellow powder
Odor	Odorless
Density	4.5 g/cm3
Melting point	600 °C (1,112 °F; 873 K) ; decomposes
Solubility in water	Insoluble
Solubility	Soluble in aq. alkalis, decompose in aqua regia; Insoluble in alkyl acetates, acetone
Structure
Crystal structure	Rhombohedral, hP3
Space group	P3m1, No. 164
Point group	3 2/m
Lattice constant	a = 3.65 Å, c = 5.88 Å α = 90°, β = 90°, γ = 120°
Coordination geometry	Octahedral (Sn4+)
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H312, H315, H319, H332, H335
Precautionary statements	P261, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P332+P313
NFPA 704 (fire diamond)	1 0 0
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Tin(IV) sulfide is a compound with the formula Sn S
₂. The compound crystallizes in the cadmium iodide motif, with the Sn(IV) situated in "octahedral holes' defined by six sulfide centers.^[5] It occurs naturally as the rare mineral berndtite.^[6] It is useful as semiconductor material with band gap 2.2 eV.^[7]

^ ^a ^b ^c Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
^ Comey, Arthur Messinger; Hahn, Dorothy A. (February 1921). A Dictionary of Chemical Solubilities: Inorganic (2nd ed.). New York: The MacMillan Company. p. 1080.
^ ^a ^b ^c ^d ^e Voort, G.F. Vander, ed. (2004). "Crystal Structure*" (PDF). ASM Handbook. 9 (Metallography and Microstructures): 29–43. doi:10.1361/asmhba0003722 (inactive 1 November 2024).{{cite journal}}: CS1 maint: DOI inactive as of November 2024 (link)^{[permanent dead link]}
^ ^a ^b ^c ^d "SDS of Stannic sulfide" (PDF). pfaltzandbauer.com. Connecticut, USA: Pfaltz & Bauer, Inc. Archived from the original (PDF) on 2014-07-14. Retrieved 2014-07-13.
^ Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.
^ Vaughan, D. J.; Craig, J. R. "Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. ISBN 0-521-21489-0.
^ L.A.Burton et al., J. Mater. Chem. A, 2016, 4, 1312-1318 DOI: 10.1039/C5TA08214E.

[crc-1] Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.

[doc00-2] Comey, Arthur Messinger; Hahn, Dorothy A. (February 1921). A Dictionary of Chemical Solubilities: Inorganic (2nd ed.). New York: The MacMillan Company. p. 1080.

[asm-3] Voort, G.F. Vander, ed. (2004). "Crystal Structure*" (PDF). ASM Handbook. 9 (Metallography and Microstructures): 29–43. doi:10.1361/asmhba0003722 (inactive 1 November 2024).{{cite journal}}: CS1 maint: DOI inactive as of November 2024 (link)^{[permanent dead link]}

[pab-4] "SDS of Stannic sulfide" (PDF). pfaltzandbauer.com. Connecticut, USA: Pfaltz & Bauer, Inc. Archived from the original (PDF) on 2014-07-14. Retrieved 2014-07-13.

[5] Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.

[6] Vaughan, D. J.; Craig, J. R. "Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. ISBN 0-521-21489-0.

[7] L.A.Burton et al., J. Mater. Chem. A, 2016, 4, 1312-1318 DOI: 10.1039/C5TA08214E.

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