Tumchaite

Tumchaite
General
CategoryPhyllosilicate
Formula
(repeating unit)
Na2(Zr,Sn)Si4O11·H2O
IMA symbolTum[1]
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/c
Unit cella = 9.144 Å, b = 8.818 Å
c = 7.537 Å, β = 113.22°; Z = 2
Identification
Formula mass462.51 g/mol
ColorColorless to white
Crystal habitPrismatic, tabular, massive, granular
Twinningon {100}
CleavagePerfect on {100}
FractureUneven
TenacityBrittle
Mohs scale hardnessClose to 4.5
LusterVitreous
StreakColorless to white
DiaphaneityTranslucent to transparent
Specific gravity2.78
Optical propertiesBiaxial (-)
Refractive indexnα = 1.570, nβ = 1.588, nγ = 1.594
Birefringenceδ = 0.0240
PleochroismColorless to greenish-gray
2V angle60 (5)°
Ultraviolet fluorescenceNone
SolubilityDoes not dissolve with dilute HCl
References[2][3][4][5]

Tumchaite, Na2(Zr,Sn)Si4O11·H2O, is a colorless to white monoclinic phyllosilicate mineral. It is associated with calcite, dolomite, and pyrite in the late dolomite-calcite carbonatites. It can be transparent to translucent; has a vitreous luster; and has perfect cleavage on {100}. Its hardness is 4.5, between fluorite and apatite. Tumchaite is isotypic with penkvilksite. The structure of the mineral is identified by silicate sheets parallel {100}, formed by alternation of clockwise and counterclockwise growing spiral chains of corner-sharing SiO4 tetrahedra. Tumchaite is named for the river Tumcha near Vuoriyarvi massif.[4]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ "Tumchaite". www.mindat.org. Retrieved 2015-12-02.
  3. ^ "Tumchaite Mineral Data". www.webmineral.com. Retrieved 2015-12-02.
  4. ^ a b Subbotin, V. V.; et., al. "Tumchaite Na2(Zr,Sn)Si4O11.H2O - A new mineral from carbonatites of the Vuoriyarvi alkali-ultrabasic massif, Murmansk Region, Russia" (PDF). The American Mineralogist. 85: 1516–1520. doi:10.2138/am-2000-1024. S2CID 53325912.
  5. ^ Mineralienatlas