Ultraviolet catastrophe

For the 1991 album by Trotsky Icepick, see The Ultraviolet Catastrophe.
The ultraviolet catastrophe is the error at short wavelengths in the Rayleigh–Jeans law (depicted as "classical theory" in the graph) for the energy emitted by an ideal black body. The error, much more pronounced for short wavelengths, is the difference between the black curve (as classically predicted by the Rayleigh–Jeans law) and the blue curve (the measured curve as predicted by Planck's law).

The ultraviolet catastrophe, also called the Rayleigh–Jeans catastrophe, was the prediction of late 19th century to early 20th century classical physics that an ideal black body at thermal equilibrium would emit an unbounded quantity of energy as wavelength decreased into the ultraviolet range.[1]: 6–7  The term "ultraviolet catastrophe" was first used in 1911 by Paul Ehrenfest,[2] but the concept originated with the 1900 statistical derivation of the Rayleigh–Jeans law.

The phrase refers to the fact that the empirically derived Rayleigh–Jeans law, which accurately predicted experimental results at large wavelengths, failed to do so for short wavelengths. (See the image for further elaboration.) As the theory diverged from empirical observations when these frequencies reached the ultraviolet region of the electromagnetic spectrum, there was a problem.[3] This problem was later found to be due to a property of quanta as proposed by Max Planck: There could be no fraction of a discrete energy package already carrying minimal energy.

Since the first use of this term, it has also been used for other predictions of a similar nature, as in quantum electrodynamics and such cases as ultraviolet divergence.

  1. ^ Cite error: The named reference VázquezHanslmeier2005 was invoked but never defined (see the help page).
  2. ^ Ehrenfest 1911
  3. ^ McQuarrie, Donald A.; Simon, John D. (1997). Physical chemistry: a molecular approach (rev. ed.). Sausalito, Calif.: Univ. Science Books. ISBN 978-0-935702-99-6.