Allotropes of plutonium

A diagram of the allotropes of plutonium at ambient pressure. Atomic volumes in cubic angstroms.
Phase Crystal structure Density (g/cm3)
alpha (α) simple monoclinic 19.86
beta (β) body-centered monoclinic 17.70
gamma (γ) face-centered orthorhombic 17.14
delta (δ) face-centered cubic 15.92
delta 
prime (δ)
body-centered tetragonal 16.00
epsilon (ε) body-centered cubic 16.51
[1]

Plutonium occurs in a variety of allotropes, even at ambient pressure. These allotropes differ widely in crystal structure and density; the α and δ allotropes differ in density by more than 25% at constant pressure.

  1. ^ Baker, Richard D.; Hecker, Siegfried S.; Harbur, Delbert R. (Winter–Spring 1983). "Plutonium: A Wartime Nightmare but a Metallurgist's Dream" (PDF). Los Alamos Science. Los Alamos National Laboratory: 148, 150–151.