Amino acid dating

Amino acid dating is a dating technique used to estimate the age of a specimen in paleobiology, molecular paleontology, archaeology, forensic science, taphonomy, sedimentary geology and other fields. This technique relates changes in amino acid molecules to the time elapsed since they were formed.[1][2][3][4][5]

All biological tissues contain amino acids. All amino acids except glycine (the simplest one) are optically active, having a stereocenter at their α-C atom. This means that the amino acid can have two different configurations, "D" or "L" which are mirror images of each other. With a few important exceptions, living organisms keep all their amino acids in the "L" configuration. When an organism dies, control over the configuration of the amino acids ceases, and the ratio of D to L moves from a value near 0 towards an equilibrium value near 1, a process called racemization. Thus, measuring the ratio of D to L in a sample enables one to estimate how long ago the specimen died.[6]

  1. ^ Bada JL (1985). "Amino Acid Racemization Dating of Fossil Bones". Annual Review of Earth and Planetary Sciences. 13: 241–268. Bibcode:1985AREPS..13..241B. doi:10.1146/annurev.ea.13.050185.001325.
  2. ^ Canoira L, García-Martínez MJ, Llamas JF, Ortíz JE, Torres TD (2003). "Kinetics of amino acid racemization (epimerization) in the dentine of fossil and modern bear teeth". International Journal of Chemical Kinetics. 35 (11): 576–591. doi:10.1002/kin.10153.
  3. ^ Bada JL, McDonald GD (1995). "Amino acid racemization on Mars: implications for the preservation of biomolecules from an extinct martian biota". Icarus. 114 (1): 139–143. Bibcode:1995Icar..114..139B. doi:10.1006/icar.1995.1049. PMID 11539479.
  4. ^ Johnson BJ, Miller GH (1997). "Archaeological Applications of Amino Acid Racemization". Archaeometry. 39 (2): 265–287. doi:10.1111/j.1475-4754.1997.tb00806.x.
  5. ^ Scarponi D, Kaufman D, Bright J, Kowalewski M (October 2008). "Quantifying time-averaging in 4th-order depositional sequences: radiocarbon-calibrated amino-acid racemization dating of Late Quaternary mollusk shells from Po Plain, Italy". Geological Society of America Abstracts with Programs. 40 (6): 502. Archived from the original on 2015-01-22. The results provide a compelling case for applicability of amino acid racemization methods as a tool for evaluating changes in depositional dynamics, sedimentation rates, time-averaging, temporal resolution of the fossil record, and taphonomic overprints across sequence stratigraphic cycles.
  6. ^ "Method". Amino acid geochronology laboratory. Northern Arizona University. Archived from the original on 2 October 2016.