Aqueous lithium-ion battery

An aqueous lithium-ion battery is a lithium-ion battery (Li-ion) that uses a concentrated saline solution as an electrolyte to facilitate the transfer of lithium ions between electrodes and induce an electrical current.[1] In contrast to non-aqueous lithium-ion batteries, aqueous Li-ion batteries are nonflammable and do not pose any significant risks of explosion, because of the water-based nature of their electrolyte. They also lack the poisonous chemicals and environmental risks associated with their non-aqueous counterparts.[2][3]

Aqueous Li-ion batteries are currently severely limited in use due to their narrow electrochemical window of stability (1.23 V). When built using conventional methods, an aqueous Li-ion has a much smaller energy density than a non-aqueous Li-ion battery and can only reach a maximum voltage of 1.5 volts. However, researchers from the University of Maryland (UMD) and the Army Research Laboratory (ARL) made it possible for an aqueous Li-ion battery to remain electrochemically stable at approximately 3.0 volts and withstand severe external damage to a degree not present in non-aqueous Li-ion batteries.[3]

  1. ^ Malik, Rahul (September 2017). "Aqueous Li-Ion Batteries: Now in Striking Distance". Joule. 1 (1): 17–19. doi:10.1016/j.joule.2017.08.016.
  2. ^ "UMD & Army Researchers Discover Salty Solution to Better, Safer Batteries". www.batterypoweronline.com. December 2, 2015. Retrieved 2018-07-10.
  3. ^ a b Suo, L.; Borodin, O.; Gao, T.; Olguin, M.; Ho, J.; Fan, X.; Luo, C.; Wang, C.; Xu, K. (2015). "'Water-in-salt' electrolyte enables high-voltage aqueous lithium-ion chemistries". Science. 350 (6263): 938–943. doi:10.1126/science.aab1595. PMID 26586759. S2CID 206637574.