Bathochromic shift

In spectroscopy, bathochromic shift (from Greek βαθύς (bathys) 'deep' and χρῶμα (chrōma) 'color'; hence less common alternate spelling "bathychromic") is a change of spectral band position in the absorption, reflectance, transmittance, or emission spectrum of a molecule to a longer wavelength (lower frequency).[1] Because the red color in the visible spectrum has a longer wavelength than most other colors, the effect is also commonly called a red shift.

Hypsochromic shift is a change to shorter wavelength (higher frequency).

  1. ^ Kamlet, Mortimer J.; Taft, R. W. (1976). "The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities". Journal of the American Chemical Society. 98 (2): 377–383. doi:10.1021/ja00418a009. ISSN 0002-7863.