Calcium disilicide

Calcium disilicide

hR9 unit cell
Identifiers
ChemSpider
ECHA InfoCard 100.031.431 Edit this at Wikidata
Properties
CaSi2
Molar mass 96.249 g/mol[1]
Appearance grey solid[1]
Density 2.50 g/cm3[1]
Melting point 1,040 °C (1,900 °F; 1,310 K)[1]
insoluble
Structure[2]
Trigonal, hR9/hR18,
R3m, No. 166
a = 0.38295/0.3855 nm, c = 1.5904/3.06 nm
3/6
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Calcium disilicide (CaSi2) is an inorganic compound, a silicide of calcium. It is a whitish or dark grey to black solid matter with melting point 1033 °C. It is insoluble in water, but may decompose when subjected to moisture, evolving hydrogen and producing calcium hydroxide. It decomposes in hot water, and is flammable and may ignite spontaneously in air.

Industrial calcium silicide usually contains iron and aluminium as the primary contaminants, and low amounts of carbon and sulfur.

  1. ^ a b c d Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.56. ISBN 1-4398-5511-0.
  2. ^ Cite error: The named reference str was invoked but never defined (see the help page).