Calcium peroxide

Calcium peroxide
Calcium peroxide
Names
Other names
  • Calcium dioxide[1]
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.013.764 Edit this at Wikidata
EC Number
  • 215-139-4
E number E930 (glazing agents, ...)
674257
KEGG
RTECS number
  • EW3865000
UNII
UN number 1457
  • InChI=1S/Ca.O2/c;1-2/q+2;-2 checkY
    Key: LHJQIRIGXXHNLA-UHFFFAOYSA-N checkY
  • InChI=1/Ca.O2/c;1-2/q+2;-2
    Key: LHJQIRIGXXHNLA-UHFFFAOYAW
  • [Ca+2].[O-][O-]
Properties
CaO2
Molar mass 72.076 g·mol−1
Appearance white or yellowish powder
Odor odorless
Density 2.91 g/cm3
Melting point ~ 355 °C (671 °F; 628 K) (decomposes)
decomposes
Acidity (pKa) 12.5
-23.8·10−6 cm3/mol
1.895
Structure
Orthorhombic[2]
Pna21
8[2]
Hazards
GHS labelling:
GHS03: OxidizingGHS07: Exclamation mark
Warning
H272, H315, H319, H335
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
Lethal dose or concentration (LD, LC):
>5000 mg/kg (oral, rat)
>10000 mg/kg (dermal, rat)
Related compounds
Other anions
Calcium oxide
Other cations
Strontium peroxide
Barium peroxide
Sodium peroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO2. It is the peroxide (O22−) salt of Ca2+. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in water.[3]

  1. ^ "Substance Registry Services | US EPA".
  2. ^ a b Zhao, X.; Nguyen, M.C.; Wang, C.Z.; Ho, K.M. (2013). "Structures and stabilities of alkaline earth metal peroxides XO2 (X = Ca, Be, Mg) studied by a genetic algorithm". RSC Advances. 3 (44): 22135. Bibcode:2013RSCAd...322135Z. doi:10.1039/C3RA43617A.
  3. ^ Jakob H, Leininger S, Lehmann T, et al. "Peroxo Compounds, Inorganic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_177.pub2. ISBN 978-3527306732.