Copper(II) chlorate

Copper(II) chlorate
Names
IUPAC name
Copper(2+) chlorate hydrate (1:2:4)
Other names
Copper(II) chlorate; Cupric chlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.035.228 Edit this at Wikidata
EC Number
  • 238-767-0
UNII
UN number 2721
  • InChI=1S/2ClHO3.Cu.4H2O/c2*2-1(3)4;;;;;/h2*(H,2,3,4);;4*1H2/q;;+2;;;;/p-2
    Key: VPXMBRBPUORXKO-UHFFFAOYSA-L
  • InChI=1S/2ClHO3.Cu/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2
    Key: IJCCOEGCVILSMZ-UHFFFAOYSA-L
  • O.O.O.O.[O-]Cl(=O)=O.[O-]Cl(=O)=O.[Cu+2]
Properties
Cu(ClO3)2•4H2O
Molar mass 302.509
Appearance Light blue
Density 2.26 g cm−3
Melting point 73 °C (anhydrous)
65 °C (hexahydrate)
Boiling point decomposes
highly water-soluble
tetrahydrate[1][2]
54.59 g/100 mL (-31 °C)
57.12 g/100 mL (-21 °C)
58.51 g/100 mL (0.8 °C)
62.17 g/100 mL (18 °C)
66.17 g/100 mL (45 °C)
69.42 g/100 mL (59.6 °C)
76.9 g/100 mL (71 °C)
hexahydrate[3]
141 g/100 mL (0 °C)
164.4 g/100 mL (18 °C)
195.6 g/100 mL (45 °C)
332 g/100 mL (70 °C)
Solubility soluble in acetone and ethanol (hexahydrate)
Structure[4]
Orthorhombic
Pcab
mmm
a = 12.924 Å, b = 9.502 Å, c = 7.233 Å
880.4 Å3
4
distorted octahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
oxidiser
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Copper(II) chlorate is a chemical compound of the transition metal copper and the chlorate anion with basic formula Cu(ClO3)2. Copper chlorate is an oxidiser.[5] It commonly forms the tetrahydrate, Cu(ClO3)2·4H2O.

  1. ^ Seidell, Atherton (1919). A. Solubilities of inorganic and organic compounds. - 3ed., vol.1 (PDF) (2 ed.). New York: D. Van Nostrand Company. p. 264. Archived from the original (PDF) on 2018-02-03. Retrieved 2018-02-01.
  2. ^ Woolley, E. M.; Miyamoto, H.; Salomon, M. (1990). Copper and Silver Halates (PDF). Elsevier. ISBN 9781483286051.
  3. ^ "copper(II) chlorate hexahydrate". chemister.ru.
  4. ^ Cite error: The named reference black was invoked but never defined (see the help page).
  5. ^ Lewis, Richard J. (2008). Hazardous Chemicals Desk Reference. John Wiley & Sons. p. 384. ISBN 9780470334454.