Corundum

Corundum
General
CategoryOxide mineral – Hematite group
Formula
(repeating unit)
Al2O3
IMA symbolCrn[1]
Strunz classification4.CB.05
Dana classification4.3.1.1
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space groupR3c (No. 167)
Unit cella = 4.75 Å, c = 12.982 Å; Z = 6
Identification
ColorColorless, gray, golden-brown, brown; purple, pink to red, orange, yellow, green, blue, violet; may be color zoned, asteriated mainly grey and brown
Crystal habitSteep bipyramidal, tabular, prismatic, rhombohedral crystals, massive or granular
TwinningPolysynthetic twinning common
CleavageNone – parting in 3 directions
FractureConchoidal to uneven
TenacityBrittle
Mohs scale hardness9 (defining mineral)[2]
LusterAdamantine to vitreous
StreakColorless
DiaphaneityTransparent, translucent to opaque
Specific gravity3.95–4.10
Optical propertiesUniaxial (−)
Refractive indexnω = 1.767–1.772
nε = 1.759–1.763
PleochroismNone
Melting point2,044 °C (3,711 °F)
FusibilityInfusible
SolubilityInsoluble
Alters toMay alter to mica on surfaces causing a decrease in hardness
Other characteristicsMay fluoresce or phosphoresce under UV light
References[3][4][5][6]
Major varieties
SapphireAny color except red
RubyRed
EmeryBlack granular corundum intimately mixed with magnetite, hematite, or hercynite

Corundum is a crystalline form of aluminium oxide (Al2O3) typically containing traces of iron, titanium, vanadium, and chromium.[3][4] It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure.[7] Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present.[7] A rare type of sapphire, padparadscha sapphire, is pink-orange.

The name "corundum" is derived from the Tamil-Dravidian word kurundam (ruby-sapphire) (appearing in Sanskrit as kuruvinda).[8][9]

Because of corundum's hardness (pure corundum is defined to have 9.0 on the Mohs scale), it can scratch almost all other minerals. It is commonly used as an abrasive on sandpaper and on large tools used in machining metals, plastics, and wood. Emery, a variety of corundum with no value as a gemstone, is commonly used as an abrasive. It is a black granular form of corundum, in which the mineral is intimately mixed with magnetite, hematite, or hercynite.[6]

In addition to its hardness, corundum has a density of 4.02 g/cm3 (251 lb/cu ft), which is unusually high for a transparent mineral composed of the low-atomic mass elements aluminium and oxygen.[10]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ "Mohs' scale of hardness". Collector's corner. Mineralogical Society of America. Retrieved 10 January 2014.
  3. ^ a b Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1997). "Corundum". Handbook of Mineralogy (PDF). Vol. III Halides, Hydroxides, Oxides. Chantilly, VA, US: Mineralogical Society of America. ISBN 0962209724. Archived (PDF) from the original on 5 September 2006.
  4. ^ a b "Corundum". Mindat.org.
  5. ^ "Corundum". Webmineral.com. Archived from the original on 25 November 2006.
  6. ^ a b Hurlbut, Cornelius S.; Klein, Cornelis (1985). Manual of Mineralogy (20th ed.). Wiley. pp. 300–302. ISBN 0-471-80580-7.
  7. ^ a b Giuliani, Gaston; Ohnenstetter, Daniel; Fallick, Anthony E.; Groat, Lee; Fagan; Andrew J. (2014). "The Geology and Genesis of Gem Corundum Deposits". Gem Corundum. Research Gate: Mineralogical Association of Canada. pp. 37–38. ISBN 978-0-921294-54-2.
  8. ^ Harper, Douglas. "corundum". Online Etymology Dictionary.
  9. ^ Jeršek, Miha; Jovanovski, Gligor; Boev, Blažo; Makreski, Petre (2021). "Intriguing minerals: corundum in the world of rubies and sapphires with special attention to Macedonian rubies". ChemTexts. 7 (3): 19. doi:10.1007/s40828-021-00143-0. ISSN 2199-3793. S2CID 233435945.
  10. ^ "The Mineral Corundum". galleries.com.