Cubanite

Cubanite
Striated, cyclically-twinned cubanite crystals from the Chibougamau mines of Quebec (size: 1.5 × 1.3 × 1.0 cm)
General
CategorySulfide mineral
Formula
(repeating unit)
CuFe2S3
IMA symbolCbn[1]
Strunz classification2.CB.55a
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPcmn
Unit cella = 6.467(1) Å,
b = 11.117(1) Å,
c = 6.231(2) Å; Z = 4
Identification
ColorBronze to brass-yellow
Crystal habitCrystals elongated to thick tabular, striated also massive
TwinningCommon with twin plane {110} in pairs, also as fourlings and pseudohexagonal sixlings
CleavageParting on {110} and {130}
FractureConchoidal
Mohs scale hardness3.5–4
LusterMetallic
StreakBlack
DiaphaneityOpaque
Specific gravity4.0–4.2
Optical propertiesDistinctly anisotropic on polished surface
Other characteristicsStrongly magnetic
References[2][3][4]

Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, cubanite falls between 3.5 and 4 and has a orthorhombic crystal system.[2] Cubanite is chemically similar to chalcopyrite; however, it is the less common copper iron sulfide mineral due to crystallization requirements.

Cubanite occurs in high temperature hydrothermal mineral deposits with pyrrhotite and pentlandite as intergrowths with chalcopyrite.[4] It results from exsolution from chalcopyrite at temperatures below 200 to 210 °C.[4] If cubanite is exposed to temperatures above 210 °C, it will transform into isocubanite. After this transformation, if it begins to cool, it will not revert to cubanite.[5] Upon its transformation to isocubanite it will lose its highly magnetic property due to its change from an orthorhombic to a cubic crystal structure.[6] Cubanite has been identified on chondrites and within dust grain samples and has improved the precision of copper isotope analysis.

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b Mindat.org
  3. ^ Webmineral
  4. ^ a b c Handbook of Mineralogy
  5. ^ Chandra, U.; Parthasarathy, G.; Sharma, P. (2010-10-01). "SYNTHETIC CUBANITE CuFe2S3: PRESSURE-INDUCED TRANSFORMATION TO ISOCUBANITE". The Canadian Mineralogist. 48 (5): 1137–1147. Bibcode:2010CaMin..48.1137C. doi:10.3749/canmin.48.5.1137. ISSN 0008-4476.
  6. ^ Sawada, M.; Ozima, M.; Fujiki, Y. (1962). "Magnetic Properties of Cubanite (CuFe2S3)". Journal of Geomagnetism and Geoelectricity. 14 (2): 107–112. Bibcode:1962JGG....14..107S. doi:10.5636/jgg.14.107. ISSN 0022-1392.