Diketene

Diketene
Names
Preferred IUPAC name
4-Methylideneoxetan-2-one
Other names
γ-Methylenepropiolactone
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.010.562 Edit this at Wikidata
EC Number
  • 211-617-1
RTECS number
  • RQ8225000
UNII
UN number 2521
  • InChI=1S/C4H4O2/c1-3-2-4(5)6-3/h1-2H2 checkY
    Key: WASQWSOJHCZDFK-UHFFFAOYSA-N checkY
  • InChI=1/C4H4O2/c1-3-2-4(5)6-3/h1-2H2
    Key: WASQWSOJHCZDFK-UHFFFAOYAM
  • O=C1OC(=C)C1
Properties
C4H4O2
Molar mass 84.074 g·mol−1
Density 1.09 g cm−3
Melting point −7 °C (19 °F; 266 K)
Boiling point 127 °C (261 °F; 400 K)
Viscosity 0.88 mPa.s
Hazards
GHS labelling:
GHS02: FlammableGHS05: CorrosiveGHS06: ToxicGHS07: Exclamation mark
Danger
H226, H301, H302, H315, H318, H330, H331, H332, H335
P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P284, P301+P310, P301+P312, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P320, P321, P330, P332+P313, P362, P370+P378, P403+P233, P403+P235, P405, P501
Flash point 33 °C (91 °F; 306 K)
275
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Diketene is an organic compound with the molecular formula C4H4O2, and which is sometimes written as (CH2CO)2. It is formed by dimerization of ketene, H2C=C=O. Diketene is a member of the oxetane family. It is used as a reagent in organic chemistry.[1] It is a colorless liquid.

  1. ^ Beilstein E III/IV 17: 4297.