Electronic effect

An electric effect influences the structure, reactivity, or properties of a molecule but is neither a traditional bond nor a steric effect.[1] In organic chemistry, the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry (stereochemistry) of a molecule.

The term polar effect is sometimes used to refer to electronic effects, but also may have the more narrow definition of effects resulting from non-conjugated substituents.[2]

  1. ^ G. L. Miessler and D. A. Tarr “Inorganic Chemistry” 3rd Ed, Pearson/Prentice Hall publisher, ISBN 0-13-035471-6.
  2. ^ "polar effect". IUPAC Gold Book. IUPAC. Retrieved 2024-02-06.