Ferroselite

Ferroselite/Dzharkenite
Ferroselite found in Argentina
General
CategorySelenide mineral
Formula
(repeating unit)
FeSe2
IMA symbolFse[1]
Strunz classification2.EB.10a
Crystal systemOrthorhombic
Space groupPnnm (no. 58)
Identification
ColorSteel-gray to tin-white with a rose tint, brass yellow
Crystal habitAcicular prismatic
TwinningStellate and cruciform twins common
Mohs scale hardness6 – 6.5
LusterMetallic
StreakBlack
Specific gravity7.20
Refractive indexOpaque
PleochroismDistinct
Solubilityinsoluble in water
References[2][3][4]

Orthorhombic ferroselite and its isometric polymorph dzharkenite are iron selenides of general formula FeSe2 precipitated under reducing conditions in anoxic environments. They are a source of selenium in the Rocky Mountains where selenium occurrence is associated with Upper Cretaceous shale deposits.

In the frame of safety assessment calculations made for deep disposal of high-level radioactive waste, ferroselite and dzharkenite are also considered in geochemical calculations as one of the mineral phases limiting the solubility of Selenium-79.[5]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Ferroselite (FeSe2) on mindat.org
  3. ^ Ferroselite (FeSe2) on webmineral.com
  4. ^ Ferroselite (FeSe2) in Handbook of Mineralogy (rruff.geo.arizona.edu)
  5. ^ "Marivoet et al. (2001) Safir 2 report. Ondraf/Niras" (PDF). Archived from the original (PDF) on 2011-04-30. Retrieved 2010-01-06.