Francium compounds

Francium compounds are compounds containing the element francium (Fr). Due to francium being very unstable, its salts are only known to a small extent. Francium coprecipitates with several caesium salts, such as caesium perchlorate, which results in small amounts of francium perchlorate. This coprecipitation can be used to isolate francium, by adapting the radiocaesium coprecipitation method of Lawrence E. Glendenin and C. M. Nelson. It will additionally coprecipitate with many other caesium salts, including the iodate, the picrate, the tartrate (also rubidium tartrate), the chloroplatinate, and the silicotungstate. It also coprecipitates with silicotungstic acid, and with perchloric acid, without another alkali metal as a carrier, which leads to other methods of separation.[1][2]

  1. ^ Hyde, E. K. (1952). "Radiochemical Methods for the Isolation of Element 87 (Francium)". J. Am. Chem. Soc. 74 (16): 4181–4184. doi:10.1021/ja01136a066. hdl:2027/mdp.39015086483156. S2CID 95854270.
  2. ^ E. N K. Hyde Radiochemistry of Francium, Subcommittee on Radiochemistry, National Academy of Sciences-National Research Council; available from the Office of Technical Services, Dept. of Commerce, 1960.