Fulminate

Fulminate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
239442
  • InChI=1S/CNO/c1-2-3/q-1 checkY
    Key: FEWJPZIEWOKRBE-UHFFFAOYSA-L checkY
  • InChI=1S/CNO/c1-2-3/q-1
    Key: USXDFAGDIOXNML-UHFFFAOYSA-N
  • [C-]#[N+][O-]
Properties
CNO
Molar mass 42.018 g·mol−1
Conjugate acid Fulminic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Fulminates are chemical compounds which include the fulminate ion (CNO, C≡N+−O). The fulminate ion is a pseudohalic ion because its charge and reactivity are similar to those of the halogens. Due to the instability of the ion, fulminate salts are friction-sensitive explosives. The best known is mercury(II) fulminate, which has been used as a primary explosive in detonators. Fulminates can be formed from metals, such as silver and mercury, dissolved in nitric acid and reacted with ethanol. The weak single nitrogen-oxygen bond is responsible for their instability. Nitrogen very easily forms a stable triple bond to another nitrogen atom, forming nitrogen gas.