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The geology of Arizona began to form in the Precambrian. Igneous and metamorphic crystalline basement rock may have been much older, but was overwritten during the Yavapai and Mazatzal orogenies in the Proterozoic. The Grenville orogeny to the east caused Arizona to fill with sediments, shedding into a shallow sea. Limestone formed in the sea was metamorphosed by mafic intrusions. The Great Unconformity is a famous gap in the stratigraphic record, as Arizona experienced 900 million years of terrestrial conditions, except in isolated basins. The region oscillated between terrestrial and shallow ocean conditions during the Paleozoic as multi-cellular life became common and three major orogenies to the east shed sediments before North America became part of the supercontinent Pangaea. The breakup of Pangaea was accompanied by the subduction of the Farallon Plate, which drove volcanism during the Nevadan orogeny and the Sevier orogeny in the Mesozoic, which covered much of Arizona in volcanic debris and sediments. The Mid-Tertiary ignimbrite flare-up created smaller mountain ranges with extensive ash and lava in the Cenozoic, followed by the sinking of the Farallon slab in the mantle throughout the past 14 million years, which has created the Basin and Range Province. Arizona has extensive mineralization in veins, due to hydrothermal fluids and is notable for copper-gold porphyry, lead, zinc, rare minerals formed from copper enrichment and evaporites among other resources.[1][2]