Grand canonical ensemble

Statistical mechanics
Thermodynamics Kinetic theory
Particle statistics Spin–statistics theorem Indistinguishable particles Maxwell–Boltzmann Bose–Einstein Fermi–Dirac Parastatistics Anyonic statistics Braid statistics
Thermodynamic ensembles NVE Microcanonical NVT Canonical µVT Grand canonical NPH Isoenthalpic–isobaric NPT Isothermal–isobaric
Models Debye Einstein Ising Potts
Potentials Internal energy Enthalpy Helmholtz free energy Gibbs free energy Grand potential / Landau free energy
Scientists Maxwell Boltzmann Helmholtz Bose Gibbs Einstein Dirac Ehrenfest von Neumann Tolman Debye Fermi Synge Ising Landau
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In statistical mechanics, the grand canonical ensemble (also known as the macrocanonical ensemble) is the statistical ensemble that is used to represent the possible states of a mechanical system of particles that are in thermodynamic equilibrium (thermal and chemical) with a reservoir.^[1] The system is said to be open in the sense that the system can exchange energy and particles with a reservoir, so that various possible states of the system can differ in both their total energy and total number of particles. The system's volume, shape, and other external coordinates are kept the same in all possible states of the system.

The thermodynamic variables of the grand canonical ensemble are chemical potential (symbol: µ) and absolute temperature (symbol: T). The ensemble is also dependent on mechanical variables such as volume (symbol: V), which influence the nature of the system's internal states. This ensemble is therefore sometimes called the µVT ensemble, as each of these three quantities are constants of the ensemble.