Hafnon | |
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General | |
Category | Nesosilicates |
Formula (repeating unit) | Hafnium silicate (HfSiO4) |
IMA symbol | Haf[1] |
Strunz classification | 09.AD.30 |
Dana classification | 51.05.02.02 |
Crystal system | Tetragonal |
Crystal class | Ditetragonal Dipyramidal (4/mmm ) H-M symbol: (4/m 2/m 2/m) |
Space group | I41/amd |
Unit cell | a = 6.5725(7) Å, c = 5.9632(4) Å=; Z = 4 |
Identification | |
Colour | Orange-red,brownish yellow, rarely colourless |
Crystal habit | Euhedral to irregular crystals |
Cleavage | {???} Indistinct |
Mohs scale hardness | 7.5 |
Luster | Vitreous |
Streak | grey white |
Diaphaneity | Transparent |
Density | 6.97 |
Optical properties | Uniaxial (+) |
Refractive index | nω = 1.930 - 1.970 nε = 1.980 - 2.030 |
Birefringence | δ = 0.050 |
Common impurities | Often zoned with zircon. Forms part of zircon-hafnon series |
Hafnon is a hafnium nesosilicate mineral, chemical formula (Hf,Zr)SiO4 or (Hf,Zr,Th,U,Y)SiO4.[2] In natural zircon ZrSiO4 part of the zirconium is replaced by the very similar hafnium and so natural zircon is never pure ZrSiO4. A zircon with 100% hafnium substitution can be made synthetically and is hafnon.
Hafnon occurs as transparent red to red orange tetragonal crystals with a hardness of 7.5.[3][4]
Hafnon occurs naturally in tantalum-bearing granite pegmatites in the Zambezia district, Mozambique and in weathered pegmatites at Mount Holland, Western Australia.[5] It has also been reported from locations in Ontario, Quebec and Manitoba, Canada; North Carolina, United States; and in Zimbabwe.[3]