Heptachlor

Heptachlor
Heptachlor
Ball-and-stick model
Names
Preferred IUPAC name
1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.000.876 Edit this at Wikidata
KEGG
UNII
  • InChI=1S/C10H5Cl7/c11-4-2-1-3-5(4)9(15)7(13)6(12)8(3,14)10(9,16)17/h1-5H checkY
    Key: FRCCEHPWNOQAEU-UHFFFAOYSA-N checkY
  • InChI=1/C10H5Cl7/c11-4-2-1-3-5(4)9(15)7(13)6(12)8(3,14)10(9,16)17/h1-5H
    Key: FRCCEHPWNOQAEU-UHFFFAOYAM
  • ClC1/C=C\C2C3(Cl)C(\Cl)=C(\Cl)C(Cl)(C12)C3(Cl)Cl
Properties
C10H5Cl7
Molar mass 373.32 g/mol
Appearance White to tan solid
Odor Camphorous
Density 1.58 g/cm3
Melting point 95 to 96 °C (203 to 205 °F; 368 to 369 K)
Boiling point 135 to 145 °C (275 to 293 °F; 408 to 418 K) at 1-1.5 mmHg
0.0006% (20°C)[1]
Vapor pressure 0.0003 mmHg (25°C)[1]
Hazards
Flash point noncombustible[1]
Lethal dose or concentration (LD, LC):
116 mg/kg (oral, guinea pig)
40 mg/kg (oral, rat)
100 mg/kg (oral, rat)
68 mg/kg (oral, mouse)
100 mg/kg (oral, hamster)[2]
50 mg/kg (cat, oral)[2]
150 mg/m3 (cat, 4 hr)
200 mg/m3 (mammal, 4 hr)[2]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.5 mg/m3 [skin][1]
REL (Recommended)
Ca TWA 0.5 mg/m3 [skin][1]
IDLH (Immediate danger)
Ca [35 mg/m3][1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Heptachlor is an organochlorine compound that was used as an insecticide. Usually sold as a white or tan powder, heptachlor is one of the cyclodiene insecticides. In 1962, Rachel Carson's Silent Spring questioned the safety of heptachlor and other chlorinated insecticides. Due to its highly stable structure, heptachlor can persist in the environment for decades. In the United States, the Environmental Protection Agency has limited the sale of heptachlor products to the specific application of fire ant control in underground transformers. The amount that can be present in different foods is regulated.[3]

  1. ^ a b c d e f NIOSH Pocket Guide to Chemical Hazards. "#0311". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ a b c "Heptachlor". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH). 4 December 2014. Retrieved 27 March 2015.
  3. ^ Robert L. Metcalf "Insect Control" in Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. doi:10.1002/14356007.a14_263