Inexact differential

An inexact differential or imperfect differential is a differential whose integral is path dependent. It is most often used in thermodynamics to express changes in path dependent quantities such as heat and work, but is defined more generally within mathematics as a type of differential form. In contrast, an integral of an exact differential is always path independent since the integral acts to invert the differential operator. Consequently, a quantity with an inexact differential cannot be expressed as a function of only the variables within the differential. I.e., its value cannot be inferred just by looking at the initial and final states of a given system.[1] Inexact differentials are primarily used in calculations involving heat and work because they are path functions, not state functions.

  1. ^ Laidler, Keith, J. (1993). The World of Physical Chemistry. Oxford University Press. ISBN 0-19-855919-4.{{cite book}}: CS1 maint: multiple names: authors list (link)