James or Jim Molyneux or Molyneaux may refer to:
- Jim Molyneux, English footballer
- James Molyneaux, Baron Molyneaux of Killead (1920–2015), MP and Ulster Unionist Party leader
- James Molyneux Caulfeild (1820–1892), Irish MP and later 3rd Earl of Charlemont
- James More Molyneux (died 1776), British politician
This disambiguation page lists articles about people with the same name.
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