Manganese(II) fluoride

Manganese(II) fluoride
Names
IUPAC name
Manganese(II) fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.054 Edit this at Wikidata
EC Number
  • 231-960-0
RTECS number
  • OP0875000
UNII
  • InChI=1S/2FH.Mn/h2*1H;/q;;+2/p-2 ☒N
    Key: CTNMMTCXUUFYAP-UHFFFAOYSA-L ☒N
  • InChI=1/2FH.Mn/h2*1H;/q;;+2/p-2
    Key: CTNMMTCXUUFYAP-NUQVWONBAJ
  • F[Mn]F
Properties
MnF2
Molar mass 92.934855 g/mol
Appearance pale pink crystalline
Density 3.98 g/cm3[1]
Melting point 856 °C (1,573 °F; 1,129 K)[1]
Boiling point 1,820 °C (3,310 °F; 2,090 K)
1.02 g/100 ml
+10,700·10−6 cm3/mol
Hazards[2]
GHS labelling:
GHS07: Exclamation mark
Warning
H302, H312, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Flash point non-flammable
Related compounds
Other anions
Manganese(II) chloride
Manganese(II) bromide
Manganese(II) iodide
Other cations
Technetium(VI) fluoride
Rhenium(VII) fluoride
Manganese(III) fluoride
Manganese(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Manganese(II) fluoride is the chemical compound composed of manganese and fluoride with the formula MnF2. It is a light pink solid, the light pink color being characteristic for manganese(II) compounds. It is made by treating manganese and diverse compounds of manganese(II) in hydrofluoric acid. Like some other metal difluorides, MnF2 crystallizes in the rutile structure, which features octahedral Mn centers.[3]

  1. ^ a b Maurice Griffel; J. W. Stout (1950). "Preparation of Single Crystals of Manganous Fluoride. The Crystal Structure from X-Ray Diffraction. The Melting Point and Density". Journal of the American Chemical Society. 72 (10): 4351–4353. doi:10.1021/ja01166a004.
  2. ^ "339288 Manganese(II) fluoride 98%". Sigma-Aldrich. Retrieved 2008-06-18.
  3. ^ Stout, J. W.; Reed, Stanley A. (1954). "The Crystal Structure of MnF2, FeF2, CoF2, NiF2 and ZnF2". J. Am. Chem. Soc. 76 (21): 5279–5281. doi:10.1021/ja01650a005.