Molar absorption coefficient

In chemistry, the molar absorption coefficient or molar attenuation coefficient (ε)[1] is a measurement of how strongly a chemical species absorbs, and thereby attenuates, light at a given wavelength. It is an intrinsic property of the species. The SI unit of molar absorption coefficient is the square metre per mole (m2/mol), but in practice, quantities are usually expressed in terms of M−1⋅cm−1 or L⋅mol−1⋅cm−1 (the latter two units are both equal to 0.1 m2/mol). In older literature, the cm2/mol is sometimes used; 1 M−1⋅cm−1 equals 1000 cm2/mol. The molar absorption coefficient is also known as the molar extinction coefficient and molar absorptivity, but the use of these alternative terms has been discouraged by the IUPAC.[2][3]

  1. ^ "Chapter 11 Section 2 - Terms and symbols used in photochemistry and in light scattering" (PDF). Compendium on Analytical Nomenclature (Orange Book). IUPAC. 2002. p. 28.
  2. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Extinction". doi:10.1351/goldbook.E02293
  3. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Absorptivity". doi:10.1351/goldbook.A00044